首页|LCST型温度敏感聚合物的研究及其在钻井液领域的应用进展

LCST型温度敏感聚合物的研究及其在钻井液领域的应用进展

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低临界溶解温度(LCST)型温度敏感聚合物是指聚合物链在相转变温度前呈伸展溶解态、相转变温度后为收缩聚集态的温度敏感型聚合物,其在环境温度变化刺激下能智能且可逆响应,已在有机化工、材料科学、生物医学和石油天然气工业等领域得到了广泛研究.该文对不同空间构象的LCST型温度敏感聚合物进行了分类,重点介绍了线形结构、温敏水凝胶、嵌段结构、接枝复合结构和特殊结构的LCST型温度敏感聚合物的研究进展;总结了不同空间构象的LCST型温度敏感聚合物在低温流变调控、温敏智能封堵、增黏提切和防漏堵漏钻井液领域的应用现状,提出了 LCST型温度敏感聚合物存在的关键问题及其在钻井液领域的应用前景.
Research on LCST-type temperature-sensitive polymers and their application progress in drilling fluids
Low critical solvation temperature(LCST)temperature-sensitive polymers are temperature-sensitive polymers whose chains present a stretch solution state before the phase transition temperature and a shrink aggregation state after the phase transition temperature.With intelligent and reversible response to ambient temperature change,LCST have been widely studied in the fields of organic chemistry,materials science,biomedicine,and oil and gas industry.In this review,LCST-type temperature-sensitive polymers with different spatial conformations were categorized,with a focus on the research progress on LCST-type temperature-sensitive polymers with linear structures,temperature-sensitive hydrogels,block structures,grafted composite structures and special structures.The application status quo of LCST-type temperature-sensitive polymers with different spatial conformations in drilling fluids,such as low-temperature rheology control,temperature-sensitive intelligent plugging,viscosity enhancement and cutting,and leakage prevention and plugging,were summarized.Finally,the key problems of LCST-type temperature-sensitive polymers and their application prospects in the field of drilling fluids were discussed.

temperature-sensitive polymersdrilling fluidslow-temperature rheology controlintelligent pluggingviscosity enhancement and cuttingleak prevention and plugging

王中义、孙金声、黄贤斌、吕开河

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中国石油大学(华东)石油工程学院,山东青岛 266580

中国石油大学(华东)非常规油气开发教育部重点实验室,山东青岛 266580

中国石油集团工程技术研究院有限公司,北京 102200

温度敏感聚合物 钻井液 低温流变调控 智能封堵 增黏提切 防漏堵漏

国家自然科学基金重大项目国家自然科学基金项目中石油科学研究与技术开发项目

51991361523740242022ZG06

2024

精细化工
大连化工研究院设计院 中国化工学会精细化工专业委员会 辽宁省化工研究院

精细化工

CSTPCD北大核心
影响因子:0.557
ISSN:1003-5214
年,卷(期):2024.41(10)
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