首页|螺吡喃类光致变色材料的改性与应用进展

螺吡喃类光致变色材料的改性与应用进展

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有机光致变色材料通过紫外光与可见光照射能够发生可逆的光异构化过程,进而实现颜色的可逆变化.螺吡喃类材料作为一类光致变色性能优异的有机材料,备受研究者的关注与青睐.通过对光照、温度、酸碱度(pH)和机械压力等多种条件的调控,螺吡喃类材料能实现高效、灵敏的变色行为.基于螺吡喃类材料的光致变色聚合物、金属有机框架和微胶囊等多种变色材料在光电信息存储、智能传感器、防伪与加密、靶向药物和荧光探针等领域具备广泛的应用前景.该文综述了螺吡喃类化合物的合成与分子结构、设计与功能化,阐明了螺吡喃类材料设计与功能化的构效关系,介绍了螺吡喃类光致变色材料的应用及最新研究热点.最后,展望了螺吡喃类材料未来的应用与发展前景.
Advances in modification and application of spiropyran-based photochromic materials
Organic photochromic materials can achieve reversible color change via reverse photoisomerization under UV and visible light irradiation.Spiropyran-based materials,a class of organic materials with excellent photochromic properties,have attracted researchers'attention and favor due to their efficient and sensitive color change behavior through regulation of light,temperature,acidity(pH),and mechanical pressure.Photochromic polymers,metal-organic frameworks,and microcapsules based on spiropyran-based compounds have wide application prospects in the fields of photoelectric information storage,intelligent sensors,anti-counterfeiting and encryption,targeted drugs and fluorescent probes.Herein,the synthesis,molecular structure,design and functionalization of spiropyran-based compounds were reviewed,and the structure-activity relationship between the design and functionalization of spiropyran-based materials was elucidated.The application and research hotspot of spiropyran-based photochromic materials were then described.Finally,the future application and development prospect of spiropyran-based materials were discussed.

photochromismspiropyransynthesisfunctionalizationphotoswitchingsmart materials

刘同力、黄从树、王晶晶、梁宇、谢志鹏、庄海燕、李九龙、朱绪飞

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南京理工大学 化学与化工学院,江苏 南京 210094

中国船舶重工集团有限公司第七二五研究所 海洋腐蚀与防护全国重点实验室,福建 厦门 361100

兰州大学 化学化工学院 功能有机分子化学国家重点实验室,甘肃 兰州 730000

光致变色 螺吡喃 合成 功能化 光开关 智能材料

2024

精细化工
大连化工研究院设计院 中国化工学会精细化工专业委员会 辽宁省化工研究院

精细化工

CSTPCD北大核心
影响因子:0.557
ISSN:1003-5214
年,卷(期):2024.41(12)