首页|四川大陆槽稀土矿床粗粒氟碳铈矿的发现及对找矿的指示意义

四川大陆槽稀土矿床粗粒氟碳铈矿的发现及对找矿的指示意义

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四川德昌大陆槽矿床是中国目前唯一确认的与隐爆作用有关的稀土矿床,具有埋藏浅、品位高、规模大等特征.氟碳铈矿是目前矿区内查明的唯一稀土工业矿物,主要分布在角砾状矿石的细粒至微细粒胶结物中.文章在大陆槽稀土矿床角砾状矿石中发现了粗粒至伟晶状氟碳铈矿,分布在含氟碳铈矿的萤石-重晶石-霓辉石角砾、含氟碳铈矿的萤石-重晶石-方解石角砾、含氟碳铈矿的方解石碳酸岩角砾中,亦呈氟碳铈矿矿物角砾.角砾中的氟碳铈矿多呈中粗粒乃至伟晶状,为板柱状自形-半自形晶体,碎裂结构发育.角砾被细粒至微细粒的石英-天青石-萤石胶结.胶结物中的氟碳铈矿呈针状、细板状或放射状集合体产出,粒度多小于100 μm.粗粒状氟碳铈矿的稀土元素氧化物含量(REO)在65%~71%之间,富铈和镧(占稀土元素总量的82%~95%),镨和钕含量相对偏低(占稀土元素总量的4%~17%);LA-ICP-MS分析获得206Pb/238U加权平均年龄为(14.78±0.27)Ma(MSWD=1.1,n=21).大陆槽稀土矿床中粗粒氟碳铈矿的存在增加了矿石的稀土品位,提升了矿床的经济价值(易于回收).同时,说明大陆槽稀土矿在隐爆作用发生之前已形成一定规模的稀土矿化,暗示矿区深部可能存在一定规模的粗粒至伟晶状脉状矿体.
Discovery of coarse-grained bastnaesite in Dalucao rare earth element deposit,Sichuan Province,and its prospecting significance
The Dalucao deposit in Sichuan Province,China,is the only confirmed rare earth deposit associated with cryptoexplosion.It is characterized by shallow burial,high-grade ore and large tonnage.Bastnaesite,the primary rare earth industrial mineral identified in this deposit,is mainly found in the fine-to-micro cements of breccia ore and is not easy observable with the naked eye.In this study,we discovered coarse-grained to pegmatitic bastnae-site in the breccia ore of the deposit.These coarse-grained bastnaesite distribute in bastnaesite-bearing aegirine augite-fluorite-barite breccia,bastnaesite-bearing fluorite-barite-calcite breccia and bastnaesite-bearing calcite car-bonate breccia,they also appear as the bastnaesite mineral breccia.The bastnaesite grains in breccia usually ex-hibit plate columnar and granular morphology,occur as euhedral or subhedral crystals with varying size of medi-um-coarse or even pegmatitic,and mostly have cataclastic texture.The breccias are cemented by fine-to-micro-grained quartz-fluorite-cerite,and the cements also contain bastnaesites in the form of acicular crystal,tabular crystal or radiate-columnar aggregate,with grain size mostly smaller than 100um.The content of rare earth ox-ides(REO)in coarse-grained bastnaesite ranges between 65%and 71%,with a higher abundance of cerium and lanthanum(accounting for 82%~95%of the total rare earth content),and relatively lower proportions of praseo-dymium and neodymium(accounting for 4%~17%of the total rare earth content);the 206Pb/238U weighted average age obtained by LA-ICP-MS is(14.78±0.27)Ma(MSWD=1.1,n=21).The occurrence of coarse-grained bastnae-site in the Dalucao deposit makes the ore having higher grade,and also enhances its economic value(higher re-coverability).Furthermore,it suggests the possible occurrence of a certain scale of rare earth mineralization in the area prior to the formation of the cryptoexplosive brecciation,this indicates the possible presence of coarse grained or pegmatitic veins containing bastnaesite at depth in the deposit.

coarse-grained bastnaesitesbreccia REE oreU-Pb ageDalucao rare earth element depositSi-chuan Province

赵芝、王登红、王伟、刘善宝、吕秉廷、何斌、班西雨

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中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室,北京 100037

成都理工大学,四川成都 610059

四川省地质矿产(集团)有限公司,四川成都 610017

中稀(凉山)稀土有限公司,四川冕宁 615600

中国地质大学(北京)地球科学与资源学院,北京 100083

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粗粒氟碳铈矿 角砾状稀土矿石 U-Pb年龄 大陆槽稀土矿床 四川省

2024

矿床地质
中国地质学会矿床地质专业委员会 中国地质科学院矿床地质研究所

矿床地质

CSTPCD北大核心
影响因子:2.163
ISSN:0258-7106
年,卷(期):2024.43(6)