首页|铝氢化钠储氢性能及其改进方法研究进展

铝氢化钠储氢性能及其改进方法研究进展

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配位氢化物NaAlH4具有较高的储氢密度且生产成本低廉,是一种典型的储氢材料;然而,较高的脱氢温度、较慢的氢吸放速率及较差的可逆性限制了其实际应用.作为一种很有前途的车载储氢介质,其储氢性能的改性研究长期备受关注.论述了NaAlH4储氢性能及其改进方法,阐明了添加催化剂和结构纳米化2种基本改进方法的原理,也阐述了理论模拟在研究NaAlH4储氢性能中的重要促进作用.
Review on hydrogen storage properties and improvement methods of the sodium aluminum hydride
The complex hydride NaAlH4 is a typical hydrogen-storage material with high hydrogen-storage density and low production cost.However,its practical application is limited due to the high dehydrogenation temperature,slow adsorption and release rate of hydrogen and poor reversibility.As a promising hydrogen-storage medium for automobiles,the improvement of its hydrogen-storage properties has attracted much attention for a long time.In this paper,the hydrogen storage properties of NaAlH4 and its improvement methods are discussed.The principles of two basic improvement methods,namely adding catalyst and structure nanoscaling,are expounded.The important role of theoretical simulation in the study of hydrogen-storage properties of NaAlH4 is also commented.The purpose of this paper is to provide some guidance for further research on hydrogen-storage properties of NaAlH4 and to realize its extensive commercial application in the field of hydrogen-energy economy.

NaAlH4chemical hydrogen storagehydrogen storage propertycatalyststructure nanoscaling

仝小刚、李志鹏、程军锋

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陇南师范高等专科学校,陇南 742500

NaAlH4 化学储氢 储氢性能 催化剂 结构纳米化

2024

科技导报
中国科学技术协会

科技导报

CSTPCD北大核心
影响因子:0.559
ISSN:1000-7857
年,卷(期):2024.42(4)
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