有机反应中的含氟与含硫新试剂
New reagents of containing fluorine and sulfur-containing in organic reactions
王乃兴1
作者信息
- 1. 中国科学院理化技术研究所,北京 100190
- 折叠
摘要
新试剂的研究和开发对有机合成具有重要意义.近年来,一些具有普遍适用性的新试剂不断出现.盘点了一些含氟和硫的官能化新试剂,如氟甲基化试剂,二氟甲基化试剂和三氟甲基化试剂,介绍了用于硫甲基化的新试剂DMSO-I2和DMSO-TsCl试剂,推介了一种用于芳香醇选择性氧化制醛的含硫新试剂Na2S2O4-TBHP.
Abstract
The research and development of new reagents are of great significance for organic synthesis.In recent years,some new reagents with universal applicability have been constantly emerging.This article introduces the latest research progress on new reagents for difluoromethylation and trifluoromethylation.Introduced some new sulfur-containing reagents.New reagents DMSO-I2 and DMSO-TsCl for sulfur methylation were introduced detailedly,The sulfur-containing reagent Na2S2O4-TBHP(TBHP,t-butylhydroperoxide)is a new reagent used for selective oxidation of aromatic alcohols to aldehydes which was also known as Wang's reagent.
关键词
新试剂/含氟试剂/含硫试剂/二氟甲基化试剂/三氟甲基化试剂/选择性氧化试剂Key words
new reagents/fluorine-containing reagents/sulfur-containing reagents/difluoromethylation reagents/trifluoromethylation reagents/selective oxidation reagents引用本文复制引用
出版年
2024
NETL
NSTL
万方数据