首页|从低品位钼钨矿硫酸浸出液中回收钼钨的实验研究

从低品位钼钨矿硫酸浸出液中回收钼钨的实验研究

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采用离子交换法从国内某公司低品位钼钨矿的硫酸浸出液中回收钼钨,对比了四种阴离子交换树脂的吸附效果,考察了温度、时间、树脂加入量和pH值对吸附效果的影响.结果表明:四种交换树脂中,弱碱性阴离子交换树脂D314的吸附效果最为良好;在D314树脂加入量2 mL,pH=1,温度60 ℃,时间6 h的最佳条件下,钼钨的吸附率分别达到89%和91%;负载树脂在以10%氢氧化钠溶液作解吸液,解吸液体积30 mL,温度25℃,时间30 min的条件下,钼钨的解吸率分别达到97%和98%.该工艺具有操作简单、可处理低浓度溶液、钼钨回收率高等优点,具有良好的发展和应用前景.
Experimental Study on the Recovery of Molybdenum and Tungsten from Sulfuric Acid Leach Solution of Low-Grade Molybdenum-Tungsten Ore
In this paper,the recovery of molybdenum and tungsten from the sulfuric acid leach solution of low-grade molybdenum and tungsten ore of a Chinese company by ion exchange method was studied,and the adsorp-tion effects of four kinds of anion exchange resins were compared,and the influences of temperature,time,resin addition and pH on the adsorption effects were investigated.The results showed that the weakly basic anion ex-change resin D314 had the most favorable adsorption effect among the four exchange resins.Under the optimal conditions of D314 resin addition of 2 mL,pH=1,temperature 60 ℃ and time 6 h,molybdenum and tungsten ad-sorption rates reached 89%and 91%,respectively.Under 10%sodium hydroxide solution as desorbent,30 mL desorbent volume,temperature 25 ℃ and time 30 min,the desorption rate of molybdenum and tungsten reached 97%and 98%,respectively.This process has good development and application prospects because of the advan-tages such as simple operation,ability to deal with low concentration solution and high recovery rate of molybde-num and tungsten.

ion exchangesulfuric acid leachaterecoverymolybdenumtungsten

张勤、高瀚杰、陈俊英、刘海鹏、杨洪英

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东北大学冶金学院,辽宁沈阳 110819

东北大学多金属矿生态冶金重点实验室,辽宁沈阳 110819

离子交换 硫酸浸出液 回收

中国黄金集团重点科研计划项目内蒙古西金矿业有限公司重点科技攻关项目

021800731220142024021800082

2024

昆明理工大学学报(自然科学版)
昆明理工大学

昆明理工大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.516
ISSN:1007-855X
年,卷(期):2024.49(4)
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