昆明理工大学学报(自然科学版)2024,Vol.49Issue(5) :21-29.DOI:10.16112/j.cnki.53-1223/n.2024.05.411

AuAl2合金阳极氧化膜的制备与耐腐蚀性能研究

Preparation and Corrosion Resistance Performance Study of AuAl2 Alloy Anodic Oxide Film

杨荣清 战明艺 于杰 崔小英 曹栋宇 唐淼 赵小青
昆明理工大学学报(自然科学版)2024,Vol.49Issue(5) :21-29.DOI:10.16112/j.cnki.53-1223/n.2024.05.411

AuAl2合金阳极氧化膜的制备与耐腐蚀性能研究

Preparation and Corrosion Resistance Performance Study of AuAl2 Alloy Anodic Oxide Film

杨荣清 1战明艺 1于杰 1崔小英 1曹栋宇 1唐淼 1赵小青1
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作者信息

  • 1. 昆明理工大学材料科学与工程学院,云南 昆明 650093
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摘要

AuAl2合金作为彩色首饰用合金材料,其成分为79%的Au和21%的Al,满足18K金比例,与其他首饰用金合金相比,呈现鲜艳的紫色,在首饰镶嵌中得到广泛应用.但其在佩戴过程中容易被汗液腐蚀.对AuAl2合金采用阳极氧化的工艺,旨在AuAl2合金表面形成Al2O3氧化层来提高AuAl2合金耐腐蚀性能.通过对真空熔炼后的AuAl2合金进行阳极氧化工艺探讨,并对阳极氧化后的AuAl2合金进行电化学工作站测试,采用扫描电子显微镜(SEM)、原子力显微镜、表面接触角测试仪、电感耦合等离子光谱发生仪(ICP)进行对比分析.实验结果表明:电解液为pH1草酸,电压为5 V,氧化时间为300 s,氧化温度为30 ℃时,耐腐蚀性能表现最佳.阳极氧化后样品的表面粗糙度增加,接触角从亲水性变为疏水性.阳极氧化膜及稀土元素Y的掺杂降低了 Al的释放量.

Abstract

The AuAl2 alloy,used as a colored jewelry alloy material,consists of 79%Au and 21%Al,meeting the ratio of 18K gold.Compared to other gold alloy materials for jewelry,it exhibits a vibrant purple color and is wide-ly applied in jewelry inlaying.However,it is susceptible to corrosion from sweat during wear.This paper employs anodic oxidation on the AuAl2 alloy with the aim of forming an Al2O3 oxidation layer on the surface to enhance the corrosion resistance of the AuAl2 alloy.The anodic oxidation process of the AuAl2 alloy after vacuum melting is discussed,and the anodically oxidized AuAl2 alloy is tested using an electrochemical workstation,Scanning E-lectron Microscope(SEM),Atomic Force Microscope,surface contact angle,and Inductively Coupled Plasma Op-tical Emission Spectrometer(ICP)for comparative analysis.The experimental findings demonstrate that when the electrolyte has a pH of 1,a voltage of 5 V,an oxidation time of 300 s,and an oxidation temperature of 30 ℃,the corrosion resistance performance is optimal.The surface roughness of the sample increases after anodic oxidation,and the contact angle changes from hydrophilic to hydrophobic.The anodic oxidation film and the doping of rare earth element Y reduce the release of Al.

关键词

阳极氧化/AuAl2合金/耐腐蚀性能/电化学

Key words

anodic oxidation/AuAl2 Alloy/corrosion resistance/electrochemistry

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基金项目

云南省重大科技专项计划项目(202302AB080005)

出版年

2024
昆明理工大学学报(自然科学版)
昆明理工大学

昆明理工大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.516
ISSN:1007-855X
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