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滇中引水工程砂化白云岩岩石学和地球化学特征

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以滇中引水工程玉溪段隧洞及沿线不同砂化等级白云岩为研究对象,通过薄片鉴定、扫描电镜(SEM)、能谱分析(EDS)及CT试验,结合化学元素和碳氧同位素分析了不同砂化等级白云岩的岩石学和地球化学特征,得到如下结论:白云岩在成岩、重结晶、胶结、白云石化及溶解作用下发育各种类型的空隙,孔隙发育及空隙数量随砂化等级的提高而增加;砂化过程中,元素的变化过程是易溶物质元素Ca、Mg流失,难溶物质元素Si、Al富集;且主量元素迁移演变特征与白云岩砂化过程呈现一定的相关性.从剧烈砂化到弱砂化,∑LREE、∑HREE和∑REE的含量逐渐减小,说明白云岩在砂化过程中经历了一定程度的淋滤丢失;稀土元素的富集随砂化程度的增强而降低,分馏程度随砂化程度的增强而增加.通过碳氧同位素中δ13CPDB和δ18OPDB的含量,计算出区分海陆相环境指标值(Z)的平均值为143.0‰,盐度(S)的平均值为30.0%,温度(T)的平均值为35.5℃.证明研究区白云岩的形成为海相成因,未受同期大气淡水影响,形成时环境盐度及海水温度较高,主量元素和微量元素在白云岩砂化过程中的地球行为较为一致.
Petrology and Geochemical Characteristics of Sandy Dolomite in the Central Yunnan Water Diversion Project
The thin section identification method,scanning electron microscope(SEM),energy dispersive spec-trometer(EDS),and CT tests,along with the examination of chemical elements and carbon and oxygen isotopes are utilized to analyze meticulously the petrology and geochemical characteristics of dolomite with varying sandifi-cation degrees along the route in Yuxi section of the Central Yunnan Water Diversion Project.The present paper concludes as follows:within diverse diagenetic environments encompassing recrystallization,cementation,dolomiti-zation,and dolomite dissolution,it is observed that the higher the degrees of sandification are,the more both pore development and void occurrence are.During the process of sandification,a distinct elemental migration is wit-nessed,characterized by the loss of calcium(Ca)and magnesium(Mg),alongside the enrichment of silicon(Si)and aluminum(Al).The characteristics of migration and evolution patterns of major elemental constituents exhibit a discernible correlation with the sandification process of dolomite.The content of ∑LREE,∑HREE,and ∑REE gradually decreased from severely to weakly sandy dolomite,indicating that dolomite experienced a certain degree of leaching loss during the sanding process;the concentration of rare earth elements decreases,and the degree of fractionation increases with the enhancement of sandification degrees.The average Marine-Terrestrial environmental indicator values(Z)value is 143.0‰,the average salinity(S)value is 30.0%,and the average temperature(T)of 35.5 ℃ are calculated out through the content of δ13CPDB and δ18OPDB in the carbon and oxy-gen isotopes.It proved that the formation of sandy dolomite is of marine origin without the impact of meteoric wa-ter in the research area,and both the environmental salinity and seawater temperature are higher during the for-mation of dolomite.The result has shown that the geochemical behaviors of major and trace elements during the process of dolomite sandification are well correlated.

Central Yunnan Water Diversion Projectsandy dolomitepetrologygeochemistry

王美乾、张长兴、刘海明、许蔚

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昆明理工大学建筑工程学院,云南 昆明 650500

昆明理工大学云南省教育厅基础设施智能运维科技创新团队,云南 昆明 650500

滇中引水工程 砂化白云岩 岩石学 地球化学

国家自然科学基金项目2022年度昆明理工大学分析测试基金项目

117620092022P2020110007

2024

昆明理工大学学报(自然科学版)
昆明理工大学

昆明理工大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.516
ISSN:1007-855X
年,卷(期):2024.49(5)