首页|中非铜钴矿带钴矿成矿特征和富集机理

中非铜钴矿带钴矿成矿特征和富集机理

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中非铜钴矿带是世界上规模大、铜钴品位高的层控型铜钴矿带,以拥有大型超大型铜钴矿床和众多的世界级铜钴矿山而闻名于世.本文综述了该成矿带的基本地质特征和矿化类型,分析了Co的超常富集机理,指出了存在的问题.中非铜钴矿带位于非洲中南部的赞比亚和刚果(金)境内,全长700 km、宽150 km,包括赞比亚铜带省矿带、赞比亚西北省矿带和刚果(金)加丹加矿带.钴矿的形成经历了裂谷期成岩成矿作用(880~735 Ma)和造山期成矿作用(530~490 Ma),分别与新元古代加丹加沉积盆地的形成发展演化和卢富里安造山作用相对应.其成因类型包括同生沉积型钴矿床和热液改造型富钴矿床.沉积型钴矿在赞比亚境内发育,钴含量相对较低;热液改造型富钴矿床在刚果(金)境内更为发育,钴含量相对较高.钴与铜共生或伴生,主要含钴矿物为硫铜钴矿、方钴矿、硫钴矿、钴黄铁矿、水钴矿、钴华、菱钴矿等.Co的超常富集与由卤水在深部交代基底岩石(矿石)形成的富金属成矿流体通过迁移-富集-沉淀作用的多期次循环有关.矿床的氧化带、原生带分带明显,局部氧化深度达到300 m,表生氧化作用往往造成钴矿化富集.该区富钴矿床整体地质研究程度较低,原生铜钴矿的成矿物质来源、成矿环境特别是铜钴超常富集机理等方面的研究需要加强.
Metallogenic characteristics and enrichment mechanism of cobalt deposits in the Central African Cu-Co metllogenic belt
The Zambian-Congo(DRC)copper cobalt metllogenic belt in the Central Africa is a large-scale and high Cu-Co graded stratabound copper-cobalt ore belt in the world.It is famous for having large and super-large copper-cobalt deposits and numerous world-class copper-cobalt mines.Many Chinese enterprises have carried out copper-cobalt deposit development in Zambia and Congo(DRC).The supernormal enrichment of cobalt is subject to a debate between the syngenetic origin and the late-stage reworking origin.Previous researches show that the formations of cobalt deposits underwent diagenesis and mineralization during the rifting period(880-735 Ma)and the mineralization during the orogeny period(530~490 Ma),which are respectively consistent with the formation,development and evolution of the Neoproterozoic Katanga sedimentary basin and the Lufilian orogeny.The formations of syngenetic sedimentary cobalt deposits and hydrothermaly reformed cobalt-rich deposits were closely related to the sedimentary environment and the multi-stage mineralization.It is considered that the supernormal enrichment of cobalt is related to the multi-stage cycling process through migration-enrichment-precipitation of metal-rich ore-forming fluids which were formed through the metasomatism of basement rocks(ores)by brine in depth.Cobalt generally intergrew with or is associated with copper.Cobalt-bearing minerals include carrollite,skutterudite,linnaeite,cobalt pyrite,heterogenite,erythrite,and spherocobaltite.Sedimentary cobalt deposits are developed in Zambia,with relatively low cobalt contents.Hydrothermally reworked cobalt deposits are relatively developed in the Democratic Republic of Congo,and they are of the sedimentary-hydrothermally reworked type of cobalt deposits.There are obvious oxidation zone and primary zone of cobalt deposits,with depth of up to 300m for the oxidation zone locally.Supergene oxidation often leads to the cobalt mineralization and enrichment.At present,in response to the overall low level of geological researches on cobalt-rich deposits in the area,it is proposed to strengthen the in-depth detailed researches on the source of ore-forming materials,ore-forming environment,especially the supernormal enrichment mechanism of copper and cobalt of primary copper-cobalt deposits.

cobalt rich depositmetallogenic characteristicsenrichment mechanismCu-Co ore belt in the Central African

莫江平、胡乔帆、方科、刘伟、周守余、李明君

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中国有色桂林矿产地质研究院有限公司,广西 桂林 541004

富钴矿床 成矿特征 富集机理 中非铜钴矿带

国家重点研发计划中国有色集团科技计划

2022YFC29035022022KJJH01

2024

矿物岩石地球化学通报
中国矿物岩石地球化学学会 中国科学院地球化学研究所

矿物岩石地球化学通报

CSTPCD北大核心
影响因子:0.912
ISSN:1007-2802
年,卷(期):2024.43(1)
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