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Cr(Ⅵ)在海陆交互区域土壤中的还原特征及主控因素

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研究海陆交互区域与内陆土壤中Cr(Ⅵ)还原特征差异及主控因素对于揭示Cr(Ⅵ)污染的行为规律和制定有效的防治策略具有重要意义.本文以海陆交互区域的烟台、深圳和内陆的长沙为对象,通过试验探究Cr(Ⅵ)的还原特征,并通过逐步回归和灰色关联度来分析主控因素.结果显示,在为期30天的实验中,温度是影响Cr(Ⅵ)还原的关键因素,与4℃的低温相比,25℃有利于提高Cr(Ⅵ)的还原速率;微生物对Cr(Ⅵ)还原的影响相对较小,而土壤中的还原物质Fe(Ⅱ)和Mn(Ⅱ),与Cr(Ⅵ)的还原速率存在一定的关联性;逐步回归和灰色关联度分析结果显示,有机质含量是影响Cr(Ⅵ)还原的重要因素,pH以及不同形态的锰和铁也对Cr(Ⅵ)还原产生影响.
Reduction characteristics and main influencing factors of Cr(Ⅵ)in soils of sea-land interaction zone
Research on the differences in Cr(Ⅵ)reduction characteristics and the main controlling factors between sea-land interaction zone and inland soils is of great significance in revealing the behavioral patterns of Cr(Ⅵ)pollution and developing effective prevention and control strategies.This study took soils from sea-land interaction zones of Yantai and Shenzhen and soils from the inland city Changsha as target soil samples,investigated the reduction behaviors of Cr(Ⅵ)by simulated experiments,and identified the main controlling factors with stepwise regression and grey correlation analysis.The results showed that temperature was the key factor affecting Cr(Ⅵ)reduction in the 30-day experiment,and the reduction rate of Cr(Ⅵ)was favored at 25℃ compared with the low temperature of 4℃;microorganisms had a relatively small effect on Cr(Ⅵ)reduction,while Fe(Ⅱ)and Mn(Ⅱ)in the soil,as the reducing substances,had a certain correlation.Furthermore,the results of stepwise regression and grey correlation analysis indicated that organic matter content was an important factor affecting Cr(Ⅵ)reduction,and pH as well as different forms of Mn and Fe also affected Cr(Ⅵ)reduction.

sea-land interaction zoneCr(Ⅵ)reduction characteristicsinfluencing factorsgrey correlation

张新颖、米兰心、陈欣彤、刘晓艳、杨文静、刘妍

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上海大学环境与化学工程学院,上海 200444

海陆交互区域 Cr(Ⅵ) 还原特征 影响因素 灰色关联

2024

矿物岩石地球化学通报
中国矿物岩石地球化学学会 中国科学院地球化学研究所

矿物岩石地球化学通报

CSTPCD北大核心
影响因子:0.912
ISSN:1007-2802
年,卷(期):2024.43(6)