科学技术与工程2024,Vol.24Issue(6) :2208-2212.DOI:10.12404/j.issn.1671-1815.2303855

变压器绝缘油老化产物的紫外可见光谱特性

UV-vis Spectral Characteristics of Aging Products of Transformer Insulating Oils

邱方程 刘荣海 何运华 胡发平 蒙高庆 任冠华
科学技术与工程2024,Vol.24Issue(6) :2208-2212.DOI:10.12404/j.issn.1671-1815.2303855

变压器绝缘油老化产物的紫外可见光谱特性

UV-vis Spectral Characteristics of Aging Products of Transformer Insulating Oils

邱方程 1刘荣海 1何运华 1胡发平 1蒙高庆 2任冠华2
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作者信息

  • 1. 云南电网有限责任公司电力科学研究院,昆明 650217
  • 2. 华北电力大学河北省物理学与能源技术重点实验室,保定 071003;华北电力大学数理系,保定 071003
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摘要

绝缘油是变压器中的重要组成物质,其品质直接影响着绝缘系统的性能以及变压器的运行安全.绝缘油老化过程将导致其绝缘及散热性能下降,进而引发故障.因此,变压器绝缘油的分析检测是了解变压器工作状态的重要手段,分析结果是变压器检修及更换新油的参考依据.利用紫外-可见吸收光谱,对不同工作年份的绝缘油进行了光谱分析,得到了绝缘油老化程度与其紫外光谱特征的关联.进一步对糠醛这一标志性老化产物的紫外光谱进行了深入研究,结合量子化学计算,解析了糠醛紫外-可见光谱特征对应的电子跃迁机制.研究结果证实了紫外-可见光谱用于分析变压器绝缘油老化程度的有效性,相关结果可作为变压器检测的参考依据.

Abstract

Insulating oil is an important component of transformers.Its quality directly affects the performance of the insulation system and the operation safety of the transformer.As working years increase,insulating oil interacts with oxygen,water,and other impurities in the environment to form a variety of aging products.This results in a decrease in its insulation and heat dissipation performance,which in turn causes failures.Therefore,analyzing and detecting transformer insulating oil is an important means to understand the working status of transformers.The analysis results are the reference basis for transformer maintenance and replacement of new oil.The ultraviolet-visible absorption spectrum was used to analyze insulating oil of different working years.The correlation between the aging degree of insulating oil and its ultraviolet spectral characteristics was obtained.The ultraviolet spectrum of furfural,a symbolic aging product,was studied by quantum chemical calculation.The mechanism corresponding to the ultraviolet-visible spectral characteristics of furfural was analyzed.The research results confirm the effectiveness of UV-visible spectroscopy in analyzing the aging degree of transformer insulating oil.The relevant results can be used as a reference for transformer detection.

关键词

紫外-可见光谱/绝缘油/糠醛/量化计算

Key words

UV-vis spectroscopy/insulating oil/furfural/quantum chemical calculation

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基金项目

云南电网科技项目(YNKJXM20220050)

河北省自然科学基金(A2021502004)

河北省高等教育教学改革研究项目(2021GJJG416)

出版年

2024
科学技术与工程
中国技术经济学会

科学技术与工程

CSTPCD北大核心
影响因子:0.338
ISSN:1671-1815
参考文献量14
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