首页|不同温度条件下天然胶乳海绵热氧老化行为

不同温度条件下天然胶乳海绵热氧老化行为

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为了分析温度对胶乳海绵在热氧老化过程中形貌与内部结构变化的影响,胶乳海绵老化后的形貌与结构变化直接影响其产品使用价值,其老化行为与温度密切相关.本文研究不局限于力学性能,通过测量70 ℃与120 ℃温度条件下胶乳海绵的白度指数、黄度指数、交联密度、压陷硬度的变化,分析了不同温度条件下材料热氧老化行为的规律.实验结果表明,120 ℃条件下黄度指数于86 h达到峰值,孔结构消失,表面生成残渣粉末,交联密度先升后降,同时压陷硬度短时间内急剧上升;70 ℃条件下材料白度指数缓慢下降,其余指标均呈缓升趋势,且孔结构完整保留.可见120 ℃条件下胶乳海绵形貌和结构在老化过程中的变化过程和最终形态与相对低温条件下存在明显差异,其产品价值因热氧老化行为极快丧失,80NR胶乳海绵抗热氧老化能力有待提高.
Thermal Oxidative Aging Behavior of Natural Latex Sponge under Different Temperature Conditions
In order to analysis the effect of temperature on thermal oxidative aging behavior of latex sponge.The morphology and structural changes of latex sponge after aging directly affect its product use value,and its aging behavior is closely related to temperature.This study is not limited to mechanical properties.By measuring the changes of whiteness index,yellowness index,crosslink density,and indentation hardness of latex sponge at 70 ℃ and 120 ℃,the thermal oxidative aging behavior of materials under different temperature conditions was analyzed.The experimental results show that the peak of the yellowness index is reached at 86 hours at 120 ℃,the pore structure disappears and residue powder is formed on the surface.The crosslinking density is initially increased first and subsequently decreased,and the indentation hardness is sharply increased in a short time.Under the condition of 70 ℃i,a slow decrease in the whiteness index of the material is noted.The other indexes display a slow upward trend,and the complete pore structure is retained.It is concluded that the change procedure and final shape of the latex sponge morphology and structure during the aging process under the condition of 120 ℃ are significantly different from those under the relatively low temperature condition.The product value is rapidly lost due to thermal oxidative aging behavior,and the thermal oxygen aging resistance of 80NR latex sponge needs improvement.

latex spongethermal oxidative agingcrosslinking densityindentation hardnessyellowness index

何森、黄冬梅、陈晨、张雪键、孔哲

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中国计量大学质量与安全工程学院,杭州 310018

浙江省特种设备检验研究院,杭州 310012

胶乳海绵 热氧老化 交联密度 压陷硬度 黄度指数

国家自然科学基金浙江省市场监督管理局雏鹰计划培育项目

51976205CY2023110

2024

科学技术与工程
中国技术经济学会

科学技术与工程

CSTPCD北大核心
影响因子:0.338
ISSN:1671-1815
年,卷(期):2024.24(6)
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