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张家口柴宣盆地浅层地下水水化学特征及水质评价

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地下水作为张家口地区的主要供水水源,近年来受人类活动影响水质有恶化的趋势,影响了当地的用水安全,确定地下水化学特征与水质状况对水资源合理利用具有重要意义.基于2020年水质数据,选取Ca2+、Mg2+、K+、Na+、HCO3-、TH、pH、TDS、SO24-、Cl-、Al3+、NO3-、F-、Cr6+等水质因子,通过数理统计法、Piper三线图、Gibbs图和岩石风化端元图对张家口柴宣盆地地区浅层地下水水化学特征进行分析,并采用模糊综合评价和改进内梅罗指数法对水质进行评价.结果表明:研究区地下水是Ca2+和HCO3-为主的弱碱性淡水,微硬水、硬水和极硬水分别占39.51%、34.57%和25.93%;沿地下水流向,地下水化学类型由HCO3-Ca·Mg、HCO3-Na、SO4·Cl-Na型转变为HCO3-Ca·Mg、HCO3-Na、SO4·Cl-Ca·Mg型,水化学组分的空间分布特征主要受到硅酸盐、碳酸盐的风化溶解和人类活动影响;地下水水质整体满足Ⅲ类标准,但部分地区水质较差;沿着地下水流向,水质逐渐变差,主要受原生地质环境和工业、农业污染的影响.
Hydrochemical Characteristics and Water Quality Evaluation of Shallow Groundwater in Chaixuan Basin,Zhangjiakou
As the main water supply source in Zhangjiakou area,the water quality of groundwater has deteriorated in recent years due to human activities,which has affected the local water safety.It is of great significance to find out the chemical characteristics and water quality of groundwater for rational utilization of water resources.Based on the water quality data of 2020,Ca2+,Mg2+,K+,Na+,HCO3,TH,pH,TDS,SO42-,Cl-,Al3+,NO3-,F-,Cr6+were selected as water quality factors.The hydro-chemical characteristics of shallow groundwater in the Chaixuan Basin of Zhangjiakou were analyzed by mathematical statistics,Piper diagram,Gibbs diagram and endmember diagram of rock weathering.The groundwater quality was evaluated by fuzzy comprehensive assessment and improved Nemerow index method.The results show that the groundwater in the study area is weakly alkaline freshwater dominated by Ca2+and HCO3-,of which micro-hard water,hard water and hardest water account for 39.51%,34.57%and 25.93%,respec-tively.The hydro-chemical types change from HCO3-Ca·Mg,HCO3-Na,SO4 Cl-Na to HCO3-Ca·Mg,HCO3-Na,SO4 Cl-Ca-Mg along the groundwater flow direction.The spatial distribution characteristics of hydro-chemical components are mainly affected by the weathering and dissolution of silicate and carbonate and human activities.The groundwater quality meets the standard of Class Ⅲ on the whole,but the groundwater quality in some areas is poor.Along the flow direction of groundwater,the water quality gradually dete-riorates,which is mainly affected by the primary geological environment and industrial and agricultural pollution.

hydrochemical characteristicswater quality assessmentfuzzy complex indeximproved Nemerow index methodprin-cipal component analysishierarchical cluster analysisChaixuan Basin

陈迎辉、马苗苗、刘月东、闫佰忠、陈莹

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河北省地质矿产勘查开发局第三地质大队,张家口 075000

河北省张承地区生态环境保护与修复技术创新中心,张家口 075000

河北省水资源可持续利用与产业结构优化协同创新中心/河北地质大学水资源与环境学院,石家庄 050000

水化学特征 水质评价 模糊综合评价 改进内梅罗指数法 主成分分析 系统聚类分析 柴宣盆地

河北省张承地区生态环境保护与修复技术创新中心项目国家自然科学基金河北省自然科学基金河北省教育厅青年拔尖项目

ZCZX20190142002251Z20200033BJK2022007

2024

科学技术与工程
中国技术经济学会

科学技术与工程

CSTPCD北大核心
影响因子:0.338
ISSN:1671-1815
年,卷(期):2024.24(7)
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