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广西思的河流域重金属污染物溶质运移模拟

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为评价广西阳朔县思的河流域矿区的重金属污染情况,将流域水文模型ArcSWAT与地下水模型(groundwater model-ing system,GMS)中MT3DMS溶质运移模块相结合,定量分析污染物锌和镉的迁移过程,为进一步的治理措施提供参考依据.结果表明:采用ArcSWAT和GMS可以更准确地确定垂向入渗量,从而准确进行地下水数值模拟.在没有防治措施的情况下,矿井废水对地下水环境造成较大的污染威胁:尾砂矿矿洞出水口水样中锌和镉的含量分别为18.62 mg/L和0.096 mg/L,是流域重金属污染的源头.模拟期20 a内,锌和镉的污染晕分别在16 d和44 d之后到达河流,前端最远距离污染晕中心分别为2 303.75 m和1 887.04 m,两端最长处为3 159.57 m和2 478.57 m,最宽处分别为1 533.54 m和1 128.36 m.锌和镉进入流域的质量分别为3 512.44 g和18.15 g,流出流域的质量为1 640.49 g和8.47 g,残留在流域的比例分别为53.28%和53.33%.根据已有研究结果表明,龙葵对镉具有较强的富集能力,在植物体中的最高富集量为1 084.4 mg/kg,并对锌具有较强的耐性,富集量也超过1 000 mg/kg.因此,设置一个模拟情景对尾矿库生态修复工程进行评价.以尾矿积水塘中锌含量0.284 mg/L和镉含量0.002 mg/L为替代污染源强,模拟期内,锌沿河谷方向的迁移速度由94.38 m/a降低至80.78 m/a,最大污染晕面积由3.80 × 106m2缩小至2.50 × 106 m2;镉的迁移速度由86.09 m/a降低至69.13 m/a,最大污染晕面积由1.67 × 106 m2缩小至1.29 × 106 m2,说明生态修复工程取得较好效果,建议继续投入建设.根据模拟预测结果,建议在矿洞出水口修建防渗帷幕等防治措施,划分污染防治区,并加强地下水水质监测,同时制定地下水风险事故应急预案,避免污染进一步加剧.
Solute Transport Simulation of Heavy Metal Contaminants in Sidi River Basin in Guangxi
In order to evaluate heavy metal contamination in Sidi River Basin mining area of Yangshuo County,Guangxi,the watershed hydrological model by ArcSWAT and the solute transport model by MT3DMS in groundwater modeling system(GMS)were combined to quantitatively analyze the migration of zinc and cadmium.The results suggest that utilizing ArcSWAT and GMS can more accurately determine the vertical infiltration amount and accurately groundwater numerical simulation.Without prevention and control measures,mine wastewater poses a significant pollution threat to groundwater environment.It is found that the content of zinc and cadmium in water sample of tailing cave outlet is 18.62 mg/L and 0.096 mg/L respectively,which is the source of heavy metal contamination in entire basin.Within simulated period of 20 years,the contaminated halo of zinc and cadmium reaches the river after about 16 d and 44 d respectively,and the farthest front end of halo is 2 303.75 m and 1 887.04 m away from the center.The longest part at both ends is 3 159.57 m and 2 478.57 m,and the widest part is 1 533.54 m and 1 128.36 m.The mass of zinc and cadmium entered basin is 3 512.44 g and 18.15 g,and flowed out is 1 640.49 g and 8.47 g,remaining proportion are 53.28%and 53.33%separately in basin.There are existing research results show that Solanum nigrum L.is hyperaccumulator for cadmium that the highest accumulation in plant is 1 084.4 mg/kg and strong tolerance to zinc with enrichment exceeding 1 000 mg/kg.Therefore,a simulated circumstance is set up to evaluate the ecological restoration of tailings reservoir.The content of zinc is 0.284 mg/L and cadmium is 0.002 mg/L in tailings pond which is taken as alternative contaminated source.The migration speed of zinc along river valley reduces from 94.38 m/a to 80.78 m/a,and cadmium reduced from 86.09 m/a to 69.13 m/a during simulated period.The maximum halo of zinc reduced from 3.80 × 1 06 m2 to 2.50 × 106 m2 and of cadmium from 1.67 × 106 m2 to 1.29 × 106 m2.It indicated that the ecological restoration has achieved better effects and proposed continue investing in construction.According to simulation results,it is recommended to construct anti-seepage curtains and other prevention measures at the mine tunnel outlet.And prevention areas are classified to strengthen groundwater quality monitoring.Simultaneously,emergency plans for groundwater accidents can be formulated to avoid further deterioration of contamination.

the Sidi River Basinheavy metal contaminationArcSWATMT3DMSsolute transport simulation

周正涛、刘明龙、夏源

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桂林理工大学环境科学与工程学院,桂林 541006

思的河流域 重金属污染 ArcSWAT MT3DMS 溶质运移模拟

国家自然科学基金广西壮族自治区科技计划

419670282020GXNSFBA297050

2024

科学技术与工程
中国技术经济学会

科学技术与工程

CSTPCD北大核心
影响因子:0.338
ISSN:1671-1815
年,卷(期):2024.24(13)
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