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多元固废基胶凝材料的组成优化及强度形成机理

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采用钢渣粉、S95矿粉、粉煤灰和脱硫石膏为原材料,通过单纯形重心方法优化设计制备多元固废胶凝材料,以胶砂抗压、抗折强度试验分析了组成成分对固废胶砂力学性能的影响,采用X射线衍射(X-ray diffraction,XRD)、傅里叶红外光谱(Fourier transform infrared spectroscopy,FT-IR)和热重(thermogravimetric,TG)方法探究了多元固废基胶凝材料强度形成机理.结果表明:多元固废基胶凝材料(SFMD)的最佳掺配比为钢渣粉∶S95矿粉∶粉煤灰∶脱硫石膏=31∶38∶27∶4.多元固废基胶砂试件的力学性能随钢渣粉掺量的增加呈先升高后降低的趋势,S95矿粉对胶砂试件早期强度贡献较大,过量的粉煤灰掺入则不利于胶砂强度的形成.SFMD的红外吸收峰在969 cm-1处出现了 C-S-H中Si—O的伸缩振动峰,且SFMD中C-S-H的失重最多,该体系的各组分之间的协同效应较好.此外,脱硫石膏可以促使钢渣粉-S95矿粉-粉煤灰体系的协同水化反应更加彻底,生成提供强度的钙矾石.
Optimization of Composition and Analysis of Strength Formation Mechanism of Multi-solid Waste-based Cementitious Materials
Steel slag powder,S95 mineral powder,fly ash and desulfurization gypsum were used as raw materials,and multifaceted solid waste cementitious materials were prepared through the optimized design of the simple shape center of gravity method.The effect of composition on the mechanical properties of solid-waste mortar was analyzed by compressive and flexural strength tests of the mortar.X-ray diffraction(XRD),Fourier infrared spectroscopy(FT-IR)and thermogravimetric(TG)methods were used to investigate the strength formation mechanism of the multifunctional solid waste-based cementitious materials.The results show that the optimal mixing ratio of multifunctional solid waste-based cementitious materials is steel slag powder∶S95 mineral powder∶fly ash∶desulfurization gypsum=31∶38∶27∶4.The mechanical properties of multifunctional solid waste-based glued sand specimens show a tendency to increase and then decrease with the increase of steel slag powder admixture.S95 mineral powder contributed more to the early strength of the glued sand specimens,while excessive fly ash admixture is detrimental to the formation of the strength of the glued sand.The infrared absorption peak of SFMD showed the telescopic vibration peak of Si—O in C-S-H at 969 cm-1,and the weight loss of C-S-H in SFMD is the most,which indicated that the synergistic effect among the components of the system is better.In addition,desulfurization gypsum can induce a more complete synergistic hydration reaction of the steel slag powder-S95 mineral powder-fly ash system to produce caliche that provides strength.

solid waste cementitious materialssteel slagcomposition designmechanical propertiesstrength formation mechanism

王强、张兴军、杜晓伟、姬海东、张斌林

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甘肃省公路交通建设集团有限公司,兰州 730030

甘肃省交通投资管理有限公司,兰州 730030

兰州交通大学土木工程学院,兰州 730070

固废胶凝材料 钢渣 组成设计 力学性能 强度形成机理

甘肃省科技重大专项甘肃省重点研发计划

22ZY1QA00522YF7GA135

2024

科学技术与工程
中国技术经济学会

科学技术与工程

CSTPCD北大核心
影响因子:0.338
ISSN:1671-1815
年,卷(期):2024.24(23)