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纳腔量子等离激元及其应用

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表面等离激元是一种由电磁波与固体中的自由电子集体振荡耦合形成的元激发,可以将光场束缚在金属与电介质界面亚波长尺度范围内,导致电磁场强度极大增强,这是等离激元光子学领域诸多物理效应和器件应用的基础.由两个或以上紧邻的金属纳米结构构成的纳米间隙是最典型的等离激元纳腔,具有最优异的光场束缚能力,可以将光场压缩到纳米尺度甚至是原子尺度.这种结构在亚纳米级的空间尺度上,隧穿、空间非局域等量子效应极其显著,导致纳腔等离激元具有许多新奇的量子特性,为新型光电器件的设计与制造提供了新的平台.尤其是最近10年来,纳腔量子等离激元在基础和应用方面都迎来了蓬勃的发展.本文首先简述了等离激元的量子化处理,回顾了亚纳米级间隙纳腔中的量子效应,重点介绍了近年在基于等离激元纳腔的量子隧穿发光、光与物质相互作用、量子光源以及精密传感等应用方向的进展,并展望了纳腔量子等离激元未来的应用方向和发展前景.
Quantum plasmonics in nanocavities and its application
Surface plasmons(SPs)are electromagnetic excitations coupled with electron waves in solid,which lead to the large negative dielectric constant of noble metals in the visible light range.They provide the ability to trap light in the nanoscale interface between the metal and the dielectric interface.Notably,ultrathin dielectric gaps between metals can trap plasmonic optical modes with surprisingly low loss and with volumes below a few tens of nm3,making it the most effective and accessible method to achieve field confinement.Plasmonic nanostructures gained rapid research interests as routes to optical devices beyond the diffraction limit of light,yielding viable nanophotonic devices,including optical metamaterials,biochemical sensing,plasmon chemistry,and nanophotonic light sources.The rapid progress in these applications has been made feasible through the availability of an extensive array of experimental tools for nanoscale fabrication,as well as robust electromagnetic simulation methods for theoretical analysis.In the meanwhile,significant interest has been devoted to the quantum properties of gap plasmons and quantum plasmonic devices that operate at the quantum level.Gap plasmonics not only helps to reveal novel quantum behaviors,which enhances fundamental understanding of quantum science,but also provides a platform for designing and manufacturing various quantum optoelectronic devices,making it an important part of the field of quantum plasmonics.Quantum plasmonics is a rapidly growing field of research that involves the study of quantum properties of light and its interaction with matter at the nanoscale.In particular,the past decade has witnessed substantial advancements in both the fundamental and applied realms of quantum plasmonics.This review presents a comprehensive overview of recent advancement in the field of quantum plasmonics within nanocavities,spanning from scientific understanding to technological applications.The discussion commences with an exploration of the quantum phenomena in plasmonic nanocavity systems,accompanied by an introduction to the development of relevant theoretical frameworks and the progress achieved through experimental investigations.Subsequently,a summary of the research and application progress in nanocavity quantum plasmonics over the past decade is provided,encompassing topics such as tunneling luminescence,light-matter interactions,quantum light sources,and high-precision sensing at the quantum level.Finally,the review concludes by highlighting pertinent challenges that demand attention and proposing novel directions for future exploration in the field.

surface plasmonnanogapquantum plasmonicsquantum deviceslight-matter interaction

徐宇浩、季嘉敏、郭全兵、吴宇、丁涛、毛力、张顺平、徐红星

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武汉大学物理科学与技术学院,武汉 430072

武汉量子技术研究院,武汉 430205

武汉大学微电子学院,武汉 430072

河南省科学院,郑州 450046

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表面等离激元 纳米间隙 量子等离激元 量子器件 光与物质相互作用

国家自然科学基金国家自然科学基金国家重点研发计划国家重点研发计划湖北省重点研发计划

12134011123743562021YFA14011042020YFA02113002022BAA016

2023

科学通报
中国科学院国家自然科学基金委员会

科学通报

CSTPCDCSCD北大核心
影响因子:1.269
ISSN:0023-074X
年,卷(期):2023.68(31)
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