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湿气发电机的研究进展、应用和展望

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随着化石资源的枯竭和环境污染的加剧,人类对绿色可再生能源的需求与日俱增.开发新型绿色能源是缓解能源危机的有效方法之一.水作为一种丰富的可再生资源,能够通过流动、蒸发、扩散等运动实现能量转换.水分子在地球表面的主要存在形式包括固态、液态和气态3种.为有效利用水资源,已制造出水力发电、潮汐能发电等使用液态水的大型设备.近年来,水分子与功能材料间的水伏效应掀起了对湿气发电的研究热潮.湿气发电机能够利用环境中的湿气能量产生电能,其过程主要包括电荷有效分离和载流子不对称运动.湿气发电机具有体积小、易制备、易集成等优点,能够从人体日常生理活动(如呼吸、出汗等)中收集能量并转化为电能,在便携式柔性电源和自供能传感器等领域具有巨大的应用潜力.本文总结了湿气发电机的基本原理、材料和结构设计方法及典型应用,并对湿气发电机的发展趋势进行了展望.
Research progress,application and perspective of moist-electric generations
With the depletion of fossil resources and the aggravation of environmental pollution,the demand for green and renewable energy is increasingly urgent.The exploration of new green energy resources is regarded as one of effective ways to alleviate the energy crisis.As a rich renewable resource,water energy can be converted into electrical energy through flow,evaporation,and diffusion.Water molecules exist on the Earth's surface mainly in solid,liquid,and gaseous forms.Currently,a variety of new energy conversion devices have developed,such as thermoelectrochemical cells,solar cells,thermoelectric generators,and triboelectric nanogenerators.Large-scale equipment that uses liquid water,such as hydroelectric power generation and tidal energy generation,has been developed for the efficient use of water resources.In recent years,the hydrovoltaic effect between water molecules and functional materials has aroused research interest in moisture generation.Common water vapor generation devices mainly include water evaporation-induced electricity generators(WEGs)which use water evaporation to generate electricity and moist-electric generations(MEGs)which absorb moisture to generate electricity.The former generates electricity through evaporation of water and the latter byabsorption of moisture.MEGs have good environmental adaptability and can spontaneously absorb moisture in the air.As an emerging green energy technology,MEGs have stimulated the research interest of scholars.The electrical circuit of MEGs is usually composed of a pair of electrodes and an active layer.The mechanisms of MEGs are complex,and the following three processes are required to achieve stable electrical output,including moisture absorption by the material layer,dissociation of functional groups,and directional movement of ions.The directional movement of ions in the power generation material layer is the main reason for the generation of direct currents,and the directional movement of ions can be achieved by the proper design of device materials and structures.In addition to the selection of different types of power generation materials,the structure design of the MEGs is equally critical to improve the output performance.Reactive electrodes and specialized structures,such as sandwiches,heterostructures,and fiber structures can also facilitate directional movement of ions.MEGs have advantages of small size,convenient preparation,and easy integration.MEGs can collect energy from daily human physiological activities(such as breathing,sweating,etc.)and convert it into electrical energy,showing great potential in portable flexible power supplies and self-powered sensors.In this paper,we summarize the basic principles,material and structure design methods,and typical applications of MEGs,and provide an outlook on the development trend of MEGs.

moist-electric generationsdirectional movement of ionsfunctional materialsdevice structureself-powered sensingenergy harvesting

韩佳欣、戴杏怡、杨景焜、吴颖辉、梁启华、曹雅钧、黄龙彪

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深圳大学物理与光电工程学院,光电子器件与系统教育部/广东省重点实验室,深圳 518060

深圳市低碳建筑材料与技术重点实验室,深圳 518060

湿气发电机 离子定向移动 功能材料 器件结构 自供能传感 能量收集

国家自然科学基金深圳市科技计划

51973119ZDSYS20220606100406016

2023

科学通报
中国科学院国家自然科学基金委员会

科学通报

CSTPCDCSCD北大核心
影响因子:1.269
ISSN:0023-074X
年,卷(期):2023.68(34)
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