首页|从红土镍矿湿法废水中回收镁和锰

从红土镍矿湿法废水中回收镁和锰

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红土镍矿湿法冶炼工艺被广泛应用于工业生产,伴随产生大量含Mn2+、Ca2+、Mg2+等有价金属的废液,选择性回收不仅能提高经济效益,还能降低废液处理的难度.以CO2为碳源,NaOH作pH值调节剂,在NaOH浓度10%、反应时间15 min、液相pH=6.6的条件下能选择性回收废液中的锰,制备含Mn41%、Ca 2.5%、Mg 0.8%的粗级碳酸锰.回收锰后的废液进一步用0.5 mol/L碳酸钠溶液调节pH值至10,回收液相中的Mg2+.此回收工艺能提高经济效益,减少湿法冶炼工艺的碳排放量,具有较高的绿色、经济应用前景.
Recovery of Mn and Mg from wet wastewater of laterite nickel ore
Laterite nickel ore hydrometallurgical process is widely used in industrial production,with a large number of valuable metals containing Mn2+,Ca2+,Mg2+waste liquid.Selective recovery can not only improve economic benefits,but also reduce the difficulty of waste liquid treatment.Using CO2 as carbon source and NaOH as pH regulator,the manganese in waste liquid can be selectively recovered under the conditions of 10%NaOH concentration,15 min reaction time and pH=6.6,and the crude manganese carbonate containing 41%Mn,2.5%Ca and 0.8%Mg can be prepared.After the recovery of manganese,the waste liquid was further adjusted to the pH value of 0.5 mol/L sodium carbonate solution to 10,and Mg2+in the liquid phase was recovered.This recovery process can improve the economic benefit line,reduce the carbon emission of the wet smelting process,and has a high green and economic application prospect.

laterite nickel orepressure leachingwastewatermanganese carbonateprecipitation

吴文卫、杜云鹏、吴咪娜、李丽娜、张文杰、李俊、左壮

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云南省生态环境科学研究院,昆明 650032

云南省重金属污染控制工程技术研究中心,昆明 655211

中南大学资源循环研究院,长沙 410083

格林美股份有限公司,深圳 518101

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红土镍矿 加压浸出 废液 碳酸锰 沉淀

云南省重大科技项目

2022AG050010

2024

矿冶
北京矿冶研究总院

矿冶

CSTPCD
影响因子:0.78
ISSN:1005-7854
年,卷(期):2024.33(1)
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