矿冶2024,Vol.33Issue(2) :271-279,309.DOI:10.3969/j.issn.1005-7854.2024.02.017

SiO制备过程添加剂影响及生产改善策略

Research on materials of the reaction vessel and heating element in the SiO production process

刘志明 袁坤 陈思明
矿冶2024,Vol.33Issue(2) :271-279,309.DOI:10.3969/j.issn.1005-7854.2024.02.017

SiO制备过程添加剂影响及生产改善策略

Research on materials of the reaction vessel and heating element in the SiO production process

刘志明 1袁坤 2陈思明3
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作者信息

  • 1. 青海盐湖元品化工有限责任公司,青海格尔木 816099;中国科学院过程工程研究所,北京 100190
  • 2. 中国科学院过程工程研究所,北京 100190;青海盐湖镁业有限公司,青海格尔木 816099
  • 3. 中国科学院过程工程研究所,北京 100190;战略金属资源绿色循环利用国家工程研究中心,北京 100190
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摘要

SiO材料是目前锂离子电池硅基负极材料中商业化应用最成熟的材料,SiO材料的工业生产主要采用SiO2与Si的蒸发法工艺,由于反应过程中反应物均为固相(或微熔融相),反应效率偏低,这一问题一直困扰着生产企业.从热力学角度出发,分析不同添加剂对SiO2+Si反应过程热力学平衡产物的分布的影响.结果表明,金属Zn对SiO2+Si反应具有较好的促进作用,并针对SiO2与Si固相反应过程物料扩散阻力大导致反应效率偏低的技术难题,提出了通过球团技术强化SiO2+Si反应过程生产改善策略,结果可为SiO实际生产过程提供一定理论参考.

Abstract

SiO is currently the most mature material in the commercial application of lithium ion battery silicon anode material,and is mainly produced the evaporation process of SiO2 and Si in industrial production.A problem of low SiO producing efficiency has been plaguing the plant since the reactants,namely SiO2 and Si are solid phase(or micro-molten phase)in the reaction process.This study analyzed the distribution of thermodynamic equilibrium products in the reaction process of SiO2+Si with different additives,and screened that metal Zn has a better promotion effect on the reaction process.Thereafter,an improvement strategy of SiO2+Si reaction process enhanced by pellet technology was proposed,to address the technical problem of low SiO producing efficiency caused by the large diffusion resistance of reactants SiO2 and Si in the solid phase reaction process.These results are expected to provide some theoretical reference for the production process of SiO in industrial production.

关键词

锂离子电池/硅基负极材料/SiO/添加剂/球团技术强化

Key words

lithium ion battery/silicon anode material/SiO/additives/pelletizing technology enhancement

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基金项目

国家自然科学基金(52004262)

出版年

2024
矿冶
北京矿冶研究总院

矿冶

CSTPCD
影响因子:0.78
ISSN:1005-7854
参考文献量23
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