首页|锂离子电池复合铜箔集流体及其制备方法

锂离子电池复合铜箔集流体及其制备方法

扫码查看
集流体作为锂离子电池汇集电流和支撑活性物质的重要结构,在高性能锂离子电池开发中占据着举足轻重的地位.相比于传统铜箔,复合铜箔是一种新型的轻质负极集流体,其独特的"Cu-聚合物-Cu"三明治结构可以显著降低集流体重量,增加电池的质量能量密度.同时,绝缘且柔韧的聚合物中间层可以阻断电子的横向传输,缓解充电过程负极嵌锂引起的膨胀应力,从而提高电池的安全性能和循环性能.介绍了复合铜箔中间层类型,评述了复合铜箔作为负极集流体的优势,总结了磁控溅射、真空蒸镀、化学镀、水电镀等典型复合铜箔制备方法,展望了复合集流体的应用前景,提出了未来需要重点关注和有待加强的研究方向和内容.
Composite copper foil current collector of lithium ion battery and preparation method
As an important structure for collecting current and supporting active substances in lithium-ion batteries,current collectors play an important role in the development of high-performance lithium-ion batteries.Compared to traditional copper foil,composite copper foil is a new type of negative collector.Its unique"Cu-polymer-Cu"sandwich structure can significantly reduce the weight of the collector and enhance the mass-energy density of the battery.Additionally,the insulating and flexible polymer interlayer can block the lateral transfer of electrons,mitigating the expansion stress caused by the lithium insertion into the anode during the charging process.Consequently,this improves the safety and cycle performance of the battery.The types of interlayers of composite copper foil are introduced,the advantages of composite copper foil as a negative current collector are reviewed,and typical preparation methods for composite copper foil,such as magnetron sputtering,vacuum evaporation,electroless plating and water electroplating,are summarized.The application prospects of composite current collectors were discussed,and research directions and contents that need to be focused on and strengthened in the future were proposed.

lithium-ion batterycomposite copper foilcurrent collectormass-energy densitycopper plating

敦雪洋、谢佳俊、王明涌

展开 >

北京科技大学绿色低碳钢铁冶金全国重点实验室,北京 100083

锂离子电池 复合铜箔 集流体 质量能量密度 镀铜

国家自然科学基金资助项目

52474373

2024

矿冶
北京矿冶研究总院

矿冶

CSTPCD
影响因子:0.78
ISSN:1005-7854
年,卷(期):2024.33(5)