首页|碱预浸渍对竹材化机浆化学成分的影响

碱预浸渍对竹材化机浆化学成分的影响

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对混合竹材采用预压榨、预浸渍、搓丝、碱液处理和盘磨机KRK磨浆,制备了竹材化机浆(CMP),并探讨碱预浸渍对竹材CMP化学成分及后续成纸的影响。研究结果表明:当预浸渍用碱量由2%(NaOH计,下同)增加至4%时,硝酸-乙醇纤维素提高率(对原竹片)由7。20%增加到17。89%。保持预浸渍用碱量4%时,将预浸渍废液替代部分预浸渍液,其中含10%预浸渍废液,即替代量为10%时,浆料含酸不溶木质素12。25%,灰分0。67%,苯-醇抽出物1。10%,聚戊糖8。47%,与未替代浆料(替代量0)相比,酸不溶木质素、灰分、苯-醇抽出物和聚戊糖降低率分别提高3。9%、13。05%、5。84%和5。95%;替代量10%时,浆料中综纤维素和硝酸-乙醇纤维素的质量分数分别为77。83%和64。71%,成浆得率67。30%(对原竹片);在打浆度为(30±0。5)度的条件下,替代量10%的浆料进行纸张抄造,成纸耐折度11次,耐破指数2。13(kPa·m2)/g,撕裂指数7。34(mN·m2)/g,裂断长3。20 km,环压指数 8。4(N·m)/g。
Effects of Alkali Pre-impregnation on the Chemical Components of Bamboo Chemi-mechanical Pulp
The mixed bamboo was treated with pre-press,pre-impregnation,thread rolling,lye and KRK pulping to prepare bamboo chemical mechanical pulp(CMP).The effects of alkali pre-impregnation on the chemical composition of bamboo CMP and the subsequent paper formation were discussed.The results showed that the improvement rate of nitric acid-ethanol cellulose(relative to the original bamboo slices)increased from 7.20%to 17.89%when the alkali dosage for pre-impregnation increased from 2%(measured by NaOH,the same below)to 4%.Replacing part of the pre-impregnation liquid with pre-impregnation waste liquid,the bamboo chips with 4%alkali for pre-impregnation was subjected to thread rolling,alkali treatment,KRK disk grinding and washing.When the substitution amount was 10%,the acid-insoluble lignin,ash,benzene-alcohol extract and polypentose contents in the pulp were 12.25%,0.67%,1.10%and 8.47%,respectively.Compared with unreplaced pulp(the substitution amount was 0),the reduction rates of acid-insoluble lignin,ash,benzene-alcohol extract and polypentose increased by 3.9%,13.05%,5.84%and 5.95%,respectively.When the substitution amount was 10%,the mass fractions of holocellulose and nitro-ethanol cellulose were 77.83%and 64.71%,respectively,and the pulp yield was 67.30%(for raw bamboo chips).At the beating degree of(30±0.5)SR and substitution amount of 10%,the folding strength,bursting index,tear index,break length and ring pressure index of the finished paper were 11 times,2.13(kPa m2)/g,7.34(mN·m2)/g,3.20 km and 8.4(N·m)/g,respectively.

pretreatmentbamboochemical compositionphysical strength

杨玲、房桂干、谢章红、韩天杰、高志杰、李文俊

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四川轻化工大学生物工程学院,四川 自贡 643000

中国林业科学研究院林产化学工业研究所,江苏南京 210042

四川省竹子制浆造纸工程技术研究中心,四川 宜宾 644000

宜宾纸业股份有限公司,四川 宜宾 644000

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预处理 竹材 化学成分 物理强度

2024

林产化学与工业
中国林业科学研究院林产化学工业研究所 中国林学会林产化学化工分会

林产化学与工业

CSTPCD北大核心
影响因子:0.696
ISSN:0253-2417
年,卷(期):2024.44(6)