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高炉富氢热储备区矿焦匹配关系模拟研究

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通过建立高炉热储备区CO、H2混合气体还原FeO矿球未反应核模型,探究煤气利用率与温度的关系,进而得到不同H2含量时,矿球还原性与焦炭反应性的匹配关系.结果表明:①还原性气体全为CO时,对于单一种矿球来说,随着热储备区温度的降低,煤气利用率受动力学和热力学共同作用,呈现升高后降低的趋势,有一个煤气利用率最大值;②富氢时,对同一种矿球来说,随着H2含量的增加,在温度为950~1000℃时,煤气利用率整体升高,煤气利用率最大值对应的温度也升高;③矿球还原性越高,匹配的焦炭反应性越高,H2含量增加1%,焦炭反应性指数需降低0.42%.
Study on the Matching Relationship between Ore and Coke in Thermal Reserve Zone under Hydrogen-rich Condition
The relationship between gas utilization rate and temperature is studied by building an unreacted nucleus model of FeO pellet reduced by CO and H2 mixture in the thermal reserve area so as to derive the matching relationship between the pellet reducibility and the coke reactivity under the condition of different H2 contents.The study results indicates:(1)for single type of ore pellet,if the reducing gas is CO only,the gas utilization rate increases first and then decreases as the tem-perature in the heat reserve area decreases under the combined action of kinetics and thermodynamics,and there is a highest value of gas utilization rate;(2)for the same type of pellets,if hydrogen is enriched,the overall utilization rate of gas at the temperature within 950-1000℃ increases along with the increase of H2 content,and the temperature corresponding to the highest value of the gas utilization rate also increases;(3)the higher the reducibility of the ore pellets,the higher the reac-tivity of the matched coke is,and the reactivity of coke needs to decrease by 0.42%for every 1%increase of H2 content.

blast furnacehydrogen-enrichmentthermal reserve zoneore reducibilitycoke reactivity

谢师威、王德全、佘雪峰、刘燕军、邓勇、薛庆国

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北京科技大学钢铁冶金新技术国家重点实验室,北京 100083

德龙钢铁有限公司,河北邢台 054009

河北省热轧板带钢技术创新中心,河北邢台 054009

华北理工大学冶金与能源学院,河北唐山 063210

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高炉 富氢 热储备区 矿石还原性 焦炭反应性

国家自然科学基金资助项目

U1960205

2024

炼铁
中冶南方工程技术有限公司

炼铁

北大核心
影响因子:0.28
ISSN:1001-1471
年,卷(期):2024.43(3)