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V含量对钒钛生铁高温氧化性能的影响

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为探究不同V含量对钒钛生铁高温氧化性能的影响规律,采用静态增重法绘制试样质量随时间变化的曲线,通过扫描电镜、能谱和XRD等分析手段研究了 800℃下不同V含量钒钛生铁的高温氧化性能.结果表明:①钒钛生铁的氧化增重与时间呈线性关系;V的加入会提高试验铁的氧化速率;②随着V含量的增加,氧化后的试样铁表面孔洞数量增多且孔径变大后趋于闭合;③铁试样中V含量较高时会造成较强的内氧化并促进Ti的氧化,当V质量分数高于0.3%,氧化层中主要氧化物为Fe2O3、V2O3和少量的TiO2,铁水凝固物的氧化程度明显上升.
Effect of V Content to Oxidation Performance of V& Ti-bearing Pig Iron under High Temperature
To study the effect law of different V contents on the oxidation performance of V & Ti-bearing pig iron under high temperature,the static additive weighing method is adopted to generate a curve of the specimen mass over time,and the oxi-dation performance of pig iron containing different V contents under 800℃ is studied by means of scanning electron microsco-py,energy spectroscopy and XRD.The results indicate:(1)the increase of oxidative weight of the V & Ti-bearing pig iron linearly relates with the time;addition of V content will increase the oxidation rate of the iron specimen;(2)with the in-crease of V content,the number of pores on the oxidized iron specimen surface increases,and after becoming larger,the pore tends to close;(3)high V content in the iron specimen will cause strong internal oxidation and promote the oxidation of Ti,when the mass fraction of V is higher than 0.3%,the main oxides in the oxidization layer are Fe2O3,V2O3 and a small a-mount of TiO2.The oxidation of hot metal solid enhances significantly also.

V & Ti-bearing pig ironV contentoxidation under high temperatureinternal oxidationoxidation mechanism

赵静瑞、张朝晖、邢相栋、折媛、权杰

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西安建筑科技大学冶金工程学院,陕西西安 710055

钒钛生铁 V含量 高温氧化 内氧化 氧化机理

陕西省自然科学基金联合基金资助项目

2019JLP-05

2024

炼铁
中冶南方工程技术有限公司

炼铁

北大核心
影响因子:0.28
ISSN:1001-1471
年,卷(期):2024.43(4)