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张宣科技氢基竖炉示范工程工艺设计特点

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对张宣科技氢基竖炉示范工程工艺设计特点进行了总结.氢基竖炉全部以焦炉煤气为气源,焦炉煤气在竖炉内实现原位重整,CH4催化裂解为CO和H2,H2/CO比可达8以上,是目前工业化生产H2比例最高的直接还原工艺.竖炉工艺气循环采用MDEA脱除CO2技术,实现炉顶煤气循环使用,可在提高还原效率、增加产量的同时,进一步减少碳排放.氢基竖炉通过采用喷钝化剂减少还原过程球团矿黏结,喷硫化物保护加热炉高温合金管,喷氧部分燃烧工艺气等"三喷"技术,不仅解决了操作安全问题,还有效提高了操作温度和反应效率,降低了系统能耗.
Process Design Features of Hydrogen-based Shaft Furnace Demonstration Project of ZXHT
The process design features of the hydrogen-based shaft furnace of ZXHT.are summarized.This shaft furnace takes COG fully as its reducing gas source,and COG undergoes in-situ reforming inside the shaft furnace,where CH4 is de-composed catalytically to CO and H2 with the H2/CO ratio up to over 8.This direct reduction process is the one which can obtain the highest percentage of H2 in the industrial production.MDEA-based CO2 removal technology is adopted in the cir-culation of the furnace process gas,which enables the top gas recycled,and can further reduce carbon emissions while impro-ving the reduction efficiency and increasing the output.The"Three Injections"technology(passivator spary on pellets to re-duce the pellet bonding during the reduction process,sulfide injection to protect the high temperature alloy pipe of the heat-er,and oxygen injection to burn the process gas partially)not only solves the operation safety problem,but also effectively increases the operating temperature,improves the reaction efficiency,and reduces the energy consumption of the system.

hydrogen-based shaft furnacecoke oven gasin-situ reformingpellet bondingalloy pipes

褚润林、路鹏、王海涛、吕志敏、闫军、曹建学

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河钢集团张宣科技氢冶金公司,河北宣化 075100

氢基竖炉 焦炉煤气 原位重整 球团矿黏结 合金管

2024

炼铁
中冶南方工程技术有限公司

炼铁

北大核心
影响因子:0.28
ISSN:1001-1471
年,卷(期):2024.43(4)