轮胎工业2024,Vol.44Issue(10) :601-605.DOI:10.12135/j.issn.1006-8171.2024.10.0601

溶聚丁苯橡胶的官能化对白炭黑/溶聚丁苯橡胶复合材料性能的影响

Effect of Functionalization of SSBR on Properties of Silica/SSBR Composite

梁雪 王鹭飞 许婧婧 董康 刘文国 陈亚婷 赵晓东 张萌萌 黄义钢 吴友平
轮胎工业2024,Vol.44Issue(10) :601-605.DOI:10.12135/j.issn.1006-8171.2024.10.0601

溶聚丁苯橡胶的官能化对白炭黑/溶聚丁苯橡胶复合材料性能的影响

Effect of Functionalization of SSBR on Properties of Silica/SSBR Composite

梁雪 1王鹭飞 1许婧婧 1董康 1刘文国 1陈亚婷 1赵晓东 1张萌萌 1黄义钢 1吴友平2
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作者信息

  • 1. 青岛双星轮胎工业有限公司,山东青岛 266400
  • 2. 北京化工大学北京市先进弹性体工程技术研究中心,北京 100029
  • 折叠

摘要

研究溶聚丁苯橡胶(SSBR)的官能化改性对白炭黑/SSBR复合材料性能的影响.结果表明:与未加入硅烷偶联剂的SSBR胶料相比,加入硅烷偶联剂的SSBR胶料的门尼粘度和转矩减小,t5延长,t90缩短;与未改性SSBR胶料相比,官能化改性SSBR胶料的硬度和10%定伸应力减小,300%定伸应力和拉伸强度增大,耐磨性能提高;白炭黑的分散性得到改善,胶料的Payne效应减弱,滞后损失和滚动阻力降低,抗湿滑性能提高.

Abstract

The effect of functionalization modification of solution-polymerized styrene butadiene rubber(SSBR)on the properties of silica/SSBR composites was investigated.The results showed that compared with the SSBR compound without silane coupling agents,the Mooney viscosity and torque of the SSBR compound with silane coupling agents decreased,t5 was prolonged,and the t90 was shortened.Compared with the unmodified SSBR compound,the hardness and modulus at 10%elongation of the functionalized modified SSBR compound decreased,the modulus at 300%elongation and tensile strength increased,and the wear resistance was improved.The dispersibility of silica was improved,the Payne effect of the compound was weakened,the hysteresis loss and the rolling resistance were reduced,and the wet slip resistance was improved.

关键词

溶聚丁苯橡胶/官能化/白炭黑/加工性能/物理性能/Payne效应/动态粘弹性

Key words

SSBR/functionalization/silica/processability/physical property/Payne effect/dynamic viscoelastic property

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出版年

2024
轮胎工业
北京橡胶工业研究设计院

轮胎工业

影响因子:0.167
ISSN:1006-8171
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