首页|改性阳离子高分子絮凝剂CS-g-ADM的制备及性能研究

改性阳离子高分子絮凝剂CS-g-ADM的制备及性能研究

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高分子絮凝剂去污法是水处理中应用最广泛的方法之一,但传统的高分子絮凝剂具有絮凝效果差、添加量大、难以循环利用和容易造成二次污染等问题.为了改善上述缺点,将丙烯酰胺和二甲基二烯丙基氯化铵两种阳离子单体接枝到壳聚糖单体,制备出了改性壳聚糖高分子絮凝剂CS-g-ADM.利用单因素实验和正交实验对合成条件进行研究,并通过扫描电镜、紫外光谱和红外光谱等测试探究了产物的表面形貌和结构.结果表明:合成的絮凝剂为一种疏松多孔的网状结构,其絮凝效果优于传统的絮凝剂,并可在较短时间和较少添加量的条件下使苋菜红、刚果红、酸性橙G三种阴离子偶氮染料的去除率达到98%以上,达到预期目的;通过再生实验证明该絮凝剂循环使用2次之后对上述阴离子染料仍具有较好的去除效果,很大程度的改善了传统高分子絮凝剂的缺点,是一种性能优良、绿色环保的絮凝剂材料.
Preparation and Properties of Modified Cationic Polymer Flocculant CS-g-ADM
Flocculant is one of the most widely used methods in water treatment,but the traditional flocculant has some problems,such as poor flocculation effect,large amount of addition,difficult to be reused and easy to cause sec-ondary pollution.In order to improve the above shortcomings,a new green polymer flocculant CS-g-ADM was pre-pared by grafting acrylamide and dimethyldiallyl ammonium chloride onto chitosan.The synthesis conditions were studied by single factor experiment and orthogonal experiment.A series of characterization methods including SEM,FTIR and UV-Vis were used to explore the morphology of the surface and component.The results show that the synthesized flocculant is a loose porous network structure,which makes the flocculation effect better than the tradi-tional flocculant.The removal rate of anion azo dyes such as amaranth red,corundum red and acid orange G can reach more than 98%under the condition of short time and less addition amount.Regeneration experiments show that the flocculant still has a good removal effect after two cycles.It greatly improves the shortcomings of traditional polymer flocculants,which is a kind of fine performance and green environmental protection flocculant material.

flocculantchitosangraft modification

何义、汤霞、魏燕

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兰州交通大学 化学化工学院,兰州 730070

絮凝剂 壳聚糖 接枝改性

甘肃省高校教师创新基金

2024B-061

2024

兰州交通大学学报
兰州交通大学

兰州交通大学学报

影响因子:0.532
ISSN:1001-4373
年,卷(期):2024.43(3)
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