首页|Epsilon-MnO2/MnFe2O4复合催化剂活化过一硫酸盐降解水中四环素的研究

Epsilon-MnO2/MnFe2O4复合催化剂活化过一硫酸盐降解水中四环素的研究

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开发高效、可持续利用的催化剂是过硫酸盐高级氧化技术发展的重点.将铁锰尖晶石MnFe2O4与ε-MnO2复合制备ε-MnO2/MnFe2O4复合催化剂,利用XRD、SEM、FTIR和XPS等方法对ε-MnO2/MnFe2O4的微观结构和形貌进行表征,并将其作为过一硫酸盐(PMS)催化剂来探究对四环素(TC,10 mg/L)的催化降解性能.结果表明:在催化剂投加0.1 g/L,PMS用量为0.05 g/L,25 ℃,pH不做调整时,90 min内对四环素的催化降解达到90.4%.实验经5次循环后TC的降解效率为76.3%,说明催化剂有较好的循环稳定性.自由基捕获实验表明降解涉及活性氧物种有:催化剂表面-OH,SO4·-,·OH,O2·-和1O2,其中催化剂表面-OH基团作起主导作用.研究制备的催化剂活化PMS对水中的抗生素有较好去除效能,具备应用潜力.
Catalytic Degradation of Tetracycline in Water by Activation of Peroxymonosulfate Using Epsilon-MnO2/MnFe2O4 as Composite Catalyst
Exploring efficient and sustainable catalysts is the focus of the development of persulfate advanced oxida-tion process.Epsilon-MnO2/MnFe2 O4 complex was synthesized with Fe-Mn spinel MnFe2O4 and ε-MnO2,the micro-structure and morphology were characterized by XRD,SEM,FTIR and XPS.The catalytic degradation performance of ε-MnO2/MnFe2 O4 was investigated by activating peroxymonosulfate(PMS)as a catalyst to degrade tetracycline(TC).The results showed that the catalytic degradation of TC could reach 90.4%in 90 min when 0.1 g/L catalyst was added,PMS dosage was 0.05 g/L,pH was not adjusted and temperature was 25 ℃.After 5 cycles of experi-ments,the degradation efficiency of ε-MnO2/MnFe2O4 activated PMS for TC was still 76.3%,which indicated that the catalyst had good cycle stability.The free radical capture experiments showed that a variety of reactive oxygen species co-contributed to the degradation of TC,such as-OH on the catalyst surface,SO4·-,·OH,O2-and 1 O2,in which the-OH group on the catalyst surface played a leading role.The prepared catalyst activated PMS had good re-moval efficiency for antibiotics in water,and therefore had potential for application.

ε-MnO2/MnFe2O4peroxymonosulfatecatalytic degradationtetracycline

李晓燕、张国珍

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兰州交通大学环境与市政工程学院,兰州 730070

兰州理工大学土木工程学院,兰州 730070

ε-MnO2/MnFe2O4 过一硫酸盐 催化降解 四环素

2024

兰州交通大学学报
兰州交通大学

兰州交通大学学报

影响因子:0.532
ISSN:1001-4373
年,卷(期):2024.43(6)