首页|高辐射热下高性能纤维阻燃织物的热防护性能研究

高辐射热下高性能纤维阻燃织物的热防护性能研究

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针对阻燃织物在高辐射热量暴露下热防护性能和力学性能均受到不同程度损失的问题,研究芳纶1313、芳纶 1414、聚酰亚胺、聚对苯撑苯并二噁唑纤维单层及芳纶 1313、芳纶 1414、聚酰亚胺混配织造的双层织物的阻燃性能、热稳定性能、40 kW/m2 辐射热通量下的热防护性能及 20 kW/m2 热通量作用后的断裂强力变化.结果表明,不同材料的单、双层织物均有较好的阻燃性能;芳纶 1313 织物在 260℃下尺寸变化率 5%左右,其他织物的尺寸变化率均在 1.5%以内;在辐射热 40 kW/m2 的热通量下,织物的辐射热防护性能与材料的耐温和织物结构有较大的关系,热分解温度较高的芳纶 1414、PBO、聚酰亚胺材料经辐射热作用后的断裂强力损失率小于 10%;当芳纶 1313/聚酰亚胺/芳纶 1414(20/30/50)双层织物接结纱间隔为 1.2 cm×1.2 cm,且表里层密度配比达到 1.6∶1时,具有较好的辐射热防护值.
Study on the thermal protection performance of high-performance fiber flame retardant fabric under high radiation heat
In view of the loss of thermal protection properties and mechanical properties of flame retardant fabrics exposed to high radiation heat exposure,the aramid 1313,aramid 1414,polyimide,polybenzene and dioxazole fiber sigle layer and aramid 1313,aramid1414,polybenzene and mixed weaving double-layer fabric of flame retardant performance,thermal stability performance,40 kW/m2 radiant heat flux and the fracture of 20 kW/m2 heat flux.The results show that the single and double-layer fabrics of different materials have good flame retardant performance;Aramid 1313 fabric size change rate about 5%at 260℃,the size change rate of the other fabrics is within 1.5%;Under the radiant heat flux of 40 kW/m2,the radiant heat protection performance of fabric has a great relationship with the material's temperature resistance and fabric structure.The breaking strength loss rate of aramid 1414,PBO and polyimide materials with higher thermal decomposition temperature is less than 10%after radiant heat action.When the interlace interval of the aramid 1313/polybenzene/aramid 1414(20/30/50)double-layer fabric is 1.2 cm×1.2 cm,and the density ratio of the outer layer and the inner layer reaches 1.6∶1,it has a better radiation heat protection value.

high performance fiberfabric structurethermal protection performancethermal stabilityflame retardant performanceair permeability

张希文、刘海、吕欢、郭晶、陈明辉

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陕西元丰新材料科技有限公司,陕西 西安 710038

高性能纤维 织物组织结构 热防护性能 热稳定性能 阻燃性能 透气性能

2024

毛纺科技
中国纺织信息中心 北京毛纺织科学研究所

毛纺科技

北大核心
影响因子:0.3
ISSN:1003-1456
年,卷(期):2024.52(11)