首页|紫外光处理DMAEA改性亚麻织物吸附性研究

紫外光处理DMAEA改性亚麻织物吸附性研究

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为了拓展纺织产品在重金属离子吸附领域的应用,以亚麻织物为原料,通过紫外光作用将丙烯酸二甲氨基乙酯(DMAEA)接枝到亚麻织物上,制得改性亚麻织物L-g-DMAEA.利用扫描电子显微镜、能量色散X射线光谱仪、傅里叶变换红外光谱仪对亚麻织物和改性产物L-g-DMAEA的形貌、结构进行了表征分析,并测试了L-g-DMAEA对Cu2+的吸附性能.结果表明:改性前后的亚麻织物对Cu2+的吸附效率从 40.64%提高至88.06%.当Cu2+初始质量浓度为400 mg/L、吸附温度为25℃、溶液pH值为7.00、吸附时间为240 min时,L-g-DMAEA对Cu2+的吸附量可达到70.40 mg/g,吸附效率为88.06%;在循环吸附5次之后L-g-DMAEA仍具有较高的吸附效率,为64.70%.吸附动力学分析表明:L-g-DMAEA对Cu2+的吸附符合准二级动力学模型,该吸附过程是物理吸附和化学吸附的结合,且以化学吸附为主.
Study on adsorption performance of DMAEA modified linen fabric with ultraviolet light
In order to expand the application of textile products in the field of heavy metal ion adsorption,linen fabric was used as raw material,and dimethylaminoethyl acrylate(DMAEA)was successfully grafted onto the fabric through UV-modification,the modified linen fabric adsorption material L-g-DMAEA was made.The morphology and chemical structure of linen fabric and modified product L-g-DMMEA were characterized and analyzed using SEM,EDX and FTIR.The adsorption performance of L-g-DMMEA was tested using Cu2+as an example.The results showed that the adsorption efficiency of Cu2+on linen fabrics before and after modification was increased from 40.64%to 88.06%.When the initial mass concentration of Cu2+was 400 mg/L,the adsorption temperature was 25℃,the solution pH value was 7.00 and the adsorption time was 240 min,the adsorption amount of L-g-DMAEA for Cu2+was 70.40 mg/g and the adsorption efficiency was 88.06%.It still had a high adsorption efficiency of 64.70%after 5 cycles.The adsorption kinetics analysis showed that the adsorption of Cu2+by L-g-DMAEA conformed to a quasi-second-order kinetic model,and the adsorption process was a combination of physical adsorption and chemical adsorption,and the chemical adsorption was dominated.

linen fabricultraviolet light treatmentdimethylamineothyl acrylateadsorption performancekinetics analysis

任冬寅、郭昊、张连秀、孙莹莹、张梅

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德州学院,山东 德州,253023

德州市功能高分子复合材料重点实验室,山东 德州,253023

山东格瑞德集团有限公司,山东 德州,253079

济南大学,山东 济南,250024

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亚麻织物 紫外光反应 丙烯酸二甲氨基乙酯 吸附性能 动力学分析

2025

棉纺织技术
陕西省纺织科学研究所 中国纺织信息中心

棉纺织技术

影响因子:0.506
ISSN:1001-7415
年,卷(期):2025.53(1)