棉纺织技术2025,Vol.53Issue(1) :48-55.

纳米氧化锡锑/聚吡咯复合导电涂层棉织物性能研究

Property study of nano antimony tin oxide/polypyrrole composite conductive coated cotton fabric

郭敏 李智慧 朱雅蕾 刘勇 黄媛 郭增革
棉纺织技术2025,Vol.53Issue(1) :48-55.

纳米氧化锡锑/聚吡咯复合导电涂层棉织物性能研究

Property study of nano antimony tin oxide/polypyrrole composite conductive coated cotton fabric

郭敏 1李智慧 2朱雅蕾 2刘勇 3黄媛 4郭增革2
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作者信息

  • 1. 山东理工大学,山东 淄博,255000;山东圣润纺织有限公司,山东 济宁,272499
  • 2. 山东理工大学,山东 淄博,255000
  • 3. 山东圣润纺织有限公司,山东 济宁,272499
  • 4. 东华大学,上海,201620
  • 折叠

摘要

为了提高柔性电子纺织品的导电性能,探究多组分导电涂层组装层数对织物性能的影响,利用浸渍-层层组装技术在棉织物基底上构筑纳米氧化锡锑/聚吡咯(ATO@WPU/PPy)双组分导电涂层,测试了不同涂层棉织物的微观结构、质量、厚度、透气性、导电性、阻燃性能及热稳定性,并与纳米氧化锡锑/聚二烯基丙二甲基氯化铵(ATO@WPU/PDDA)单组分导电涂层织物进行对比.结果表明:随着ATO@WPU/PPy组装层数的增加,棉织物表面涂层负载量提高,双组分复合导电涂层棉织物的表面电阻降低,最低为1.4 kΩ/sq,而相同组装层数的ATO@WPU/PDDA单组分导电涂层织物表面电阻为37.3 kΩ/sq,说明双组分复合涂层棉织物的导电性明显提高,且ATO@WPU/PPy双组分复合涂层棉织物的阻燃性能及热稳定性也逐渐提高.认为:制备的双组分导电涂层棉织物性能优于单组分导电涂层织物,其在开发柔性电子纺织器件方面具有优势.

Abstract

In order to improve the electrical conductivity of flexible electronic textiles and explore the influence of layers for multiple components electrical coated layer assembly on fabric property,the nano antimony tin oxide/polypyrrole(ATO@WPU/PPy)bio-component conductive coating was constructed on cotton fabric substrate by dipping-assisted layer-by-layer assembly technique.The microstructure,quality,thickness,permeability,electrical conductivity,flame retardancy and thermal stability of different coated cotton fabrics were tested and compared with nano antimony tin oxide/poly dimethyl diallyl ammonium chloride(ATO@WPU/PDDA)single component conductive coated fabric.The results showed that with the increase of ATO@WPU/PPy assembly layer,the surface coating load of cotton fabrics was increased,and the surface resistance of the bio-component composite conductive coated cotton fabric was decreased,the lowest was 1.4 kΩ/sq,while the surface resistance of the ATO@WPU/PDDA single-component conductive coated fabric with the same assembly layers was 37.3 kΩ/sq.It indicated that the electrical conductivity of the bio-component composite coated cotton fabric was significantly improved.The flame retardancy and thermal stability of ATO@WPU/PPy composite coated cotton fabric were also gradually improved.It is considered that the performance of the prepared cotton fabric with bio-component conductive coating is better than that of the fabric with single-component conductive coating.It has advantages in the development of flexible electronic textile devices.

关键词

氧化锡锑/聚吡咯/层层组装/涂层织物/导电性/阻燃性

Key words

antimony tin oxide/polypyrrole/layer-by-layer assembly/coated fabric/electrical conductivity/flame retardancy

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出版年

2025
棉纺织技术
陕西省纺织科学研究所 中国纺织信息中心

棉纺织技术

影响因子:0.506
ISSN:1001-7415
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