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涤纶纤维上ZnO纳米棒阵列生长及光催化性能研究

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采用射频磁控溅射法在涤纶纤维上沉积ZnO籽晶层,在ZnO籽晶层上水热生长ZnO 纳米棒阵列,通过在紫外线照射下降解罗丹明B研究了样品的光催化活性,用表面光电压(SPV)谱研究了ZnO 纳米棒阵列表面内建电场.光催化性能测试结果显示,反应 180 min后ZnO纳米棒阵列/涤纶样品和ZnO薄膜/涤纶样品的罗丹明B降解率分别为 81%和 33%,表明ZnO纳米棒阵列/涤纶样品的光催化活性显著大于ZnO薄膜/涤纶样品.SPV测试分析表明,ZnO纳米棒阵列表面存在较强内建电场,其方向由纳米棒体内指向表面.表面内建电场有利于光生电子、空穴的分离,进而提高了光催化反应的效率.
Preparation of ZnO Nanorod Arrays on Polyster Fiber and Study of the Photocatalytic Performance
In this article,we used RF magnetron sputtering to deposit ZnO seed layers on polyester fi-bers,and hydrothermally synthesize ZnO nanorod arrays on the seed layers.The photocatalytic activity of the samples was studied by degrading Rhodamine B under UV irradiation.The surface built-in electric field of the ZnO nanorod array was studied using surface photovoltage(SPV)spectroscopy.The photo-catalytic performance test results showed that after 180 minutes of reaction,the degradation rates of Rhodamine B in ZnO nanorod array/polyester sample and ZnO film/polyester sample were 81%and 33%respectively,indicating that the photocatalytic activity of ZnO nanorod array/polyester sample was significantly higher than that of ZnO film/polyester sample.SPV testing analysis shows that there is a strong built-in electric field on the surface of the ZnO nanorod array,which is directed from the nanorod body to the surface.The built-in electric field on the surface is conducive to the separation of photo gen-erated electrons and holes,thereby improving the efficiency of photocatalytic reactions on ZnO.

photocatalysisZnO nanorod arraypolyster fabricsurface built-in electric field

郑辉、杨若冰、邱晗、林志颖、吴寿强

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闽江学院物理与电子信息工程学院,福建 福州 350108

光催化 ZnO纳米棒阵列 涤纶织物 表面内建电场

2024

闽江学院学报
闽江学院

闽江学院学报

CHSSCD
影响因子:0.221
ISSN:1009-7821
年,卷(期):2024.45(5)