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高硫煤矸石理化性质表征及污染防治探究

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通过调研了解贵州六盘水煤矸石堆场及利用现状,以高硫煤矸石为试样进行理化性质分析,探索再加工利用途径,并模拟堆场情况,在不同粒度、不同浸泡时间条件下,分析高硫煤矸石浸出液中主要金属和有毒有害元素含量变化趋势及浸出特征.结果表明:高硫煤矸石中SiO2、Al2O3、Fe2O3 含量较高,可作为新材料原料再次回收加工利用.高硫煤矸石浸出液中Fe、Mn、Pb、Cd含量相对较高,变化趋势与SO42-基本一致,可采用脱硫,添加碱性材料、菌株等无害化措施将硫分降低,减少活化条件.新鲜的高硫煤矸石产酸风险非常高,释放周期长,经预处理,硫分达到堆填标准后,仍应着重定期监测,防止潜在污染风险.研究结果可对高硫煤矸石再加工利用、复垦及堆场环境防治提供参考.
The physical&chemical characterization of high sulfur coal gangue and the exploration of pollution control
By conducting research to understand the current status of the Liupanshui coal gangue storage yard and utilization in Guizhou,physical and chemical properties of high sulfur coal gangue were analyzed as samples to explore ways of reprocessing and utilization.The situation of the storage yard was simulated,and the trends and leaching characteristics of the main metals and toxic and harmful elements in the leaching solution of high sulfur coal gangue were analyzed under different particle sizes and soaking times.The results indicate that high sulfur coal gangue has a high content of SiO2,Al2O3,and Fe2O3,which can be recycled and processed as new material raw materials.The content of Fe,Mn,Pb,and Cd in the leaching solution of high sulfur coal gangue is relatively high,and the trend of change is basically consistent with that of SO42-.Harmless measures such as desulfurization,adding alkaline materials,and bacterial strains can be used to reduce sulfur content and minimize activation conditions.Fresh high sulfur coal gangue has a very high risk of acid production and a long release cycle.Even after the sulfur content reaches the landfill standard through pre-treatment,regular monitoring should still be emphasized to prevent potential pollution risks.The research results can provide reference for the recycling,reclamation,and environmental prevention of high sulfur coal gangue.

high sulfur coalphysical&chemical characterizationleaching solutionpollution control

李远

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贵州省煤炭产品质量监督检验院,贵州 六盘水 553001

高硫煤矸石 理化性质 浸出液 污染防治

2024

煤炭加工与综合利用
中国煤炭加工利用协会

煤炭加工与综合利用

影响因子:0.496
ISSN:1005-8397
年,卷(期):2024.(12)