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滁河南京段环境介质中环状挥发性甲基硅氧烷的污染水平与生态风险评价

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环状挥发性甲基硅氧烷(cVMSs)因进入环境后存在潜在生态风险而受到广泛关注。研究采样测定滁河南京段地表水、沉积物及周边土壤中八甲基环四硅氧烷(D4)、十甲基环五硅氧烷(D5)和十二甲基环六硅氧烷(D6)3 种cVMSs的浓度水平,并对其生态风险进行了评价。结果表明:地表水中D4、D5、D6 的检出率分别为 38。1%、95。2%、100%,总含量范围为 13。66~77。90 ng·L-1,平均值为 47。82 ng·L-1;沉积物中D4、D5、D6 的检出率分别为 66。7%、86。7%、100%,总含量范围为 0。56~49。74 μg·kg-1,平均值为 13。95 μg·kg-1;土壤中D4、D5、D6 的检出率分别为 66。7%、20%、100%,总含量范围为 1。90~7。05 μg·kg-1,平均值为 3。57 μg·kg-1。地表水和土壤中D6 的检出浓度最高,沉积物中则为D5,对比国内外其他地区的相关结果,cVMSs处于中低水平。生态风险评价结果显示,滁河南京段水体中cVMSs存在中高风险。
Pollution Level and Ecological Risk Assessment of Cyclic Volatile Methylsiloxanes in the Environmental Media in Nanjing Section of Chuhe River
Cyclic volatile methylsiloxane(cVMSs)has attracted extensive attention due to its potential ecological risks af-ter entering the environment.In this study,the samples were collected to analyze concentrations of octamethylcyclotetrasi-loxane(D4),decamethylcyclopentasiloxane(D5)and dodecamethylcyclohexasiloxane(D6)in the surface water,sedi-ment and surrounding soil of Nanjing section of Chuhe River,and their ecological risks were evaluated.The results show that the detection rates of D4,D5 and D6 in surface water were 38.1%,95.2%and 100%,respectively,and the range of total concentration of cVMSs was13.66-77.90 ng·L-1,with an average of 47.82 ng·L-1.The detection rates of D4,D5 and D6 in the sediments were 66.7%,86.7%and 100%,respectively,and the range of total concentration of cVMSs was 0.56-49.74 μg·kg-1,with an average of 13.95 μg·kg-1.The detection rates of D4,D5 and D6 in the soils were 66.7%,20%and100%,respectively,and the range of total concentration of cVMSs was1.90-7.05 μg·kg-1,with an average of 3.57 μg·kg-1.The highest detected concentration of D6 was in surface water and soil,while in sediment it was D5.Compared with the results from other regions at home and abroad,concentrations of cVMSs in Nanjing Section of Chu-he River were in the middle-low level.The ecological risk assessment results show a medium/high risk of cVMSs in Nan-jing section of Chuhe River.

methylsiloxanesecological riskconcentration levelNanjing section of Chuhe River

张伟、古文、范德玲、张冰、王蕾、石利利

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南京信息工程大学环境科学与工程学院,江苏 南京 210044

生态环境部南京环境科学研究所, 江苏 南京 210042

甲基硅氧烷 生态风险 浓度水平 滁河南京段

生态环境部南京环境科学研究所创新团队建设项目国家重点研发计划

ZX2023QT0032018YFC1801601

2024

生态与农村环境学报
环境保护总局南京环境科学研究所

生态与农村环境学报

CSTPCDCHSSCD北大核心
影响因子:1.248
ISSN:1673-4831
年,卷(期):2024.40(2)
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