首页|利用原状磷石膏制备石膏基复合胶凝材料的力学性能

利用原状磷石膏制备石膏基复合胶凝材料的力学性能

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以未经处理的原状磷石膏制备磷石膏基复合胶凝材料,测试磷石膏基复合胶凝材料的力学性能,考察生石灰的掺量、水灰比以及成型压力对磷石膏基复合胶凝材料力学性能的影响.结果表明:当生石灰掺量为4%时,磷石膏-矿渣复合胶凝材料具有较好的力学性能,矿渣微粉对磷石膏-粉煤灰复合胶凝材料的力学性能有增强作用.对于磷石膏-矿渣-炉渣复合胶凝材料,当成型压力超过3MPa时,制备的材料力学性能明显下降.同浇注成型试样相比较,在5MPa成型压力下的压实成型试样,材料孔隙率提高,特别对于200nm以上孔所占体积分数来说,其所占体积分数要远远高于浇注成型试样,导致了材料微观结构劣化,力学性能变差.
Mechanical property of phosphogypsum based composite cementing material prepared with original phosphogypsum
Original untreated phosphogypsum was used to prepare a kind of phosphogypsum based cementing material, the mechanical property of the prepared material was tested and effects of quicklime content, water/cement ratio and molding pressure on the mechanical property were investigated. The results showed that with the quicklime content of 4%, the phosphogypsum slag composite cementing material had a good mechanical property, slag power had a positive correlation with the mechanical property of the phosphogypsum fly ash composite cementing material, and the mechanical property of the phosphogypsum slag boiler slag composite cementing material decreased as the molding pressure was greater than 3 MPa. Compared with the specimens prepared by casting molding method, the total porosity value of the specimens prepared under 5 MPa molding pressure was larger, especially for the volume fraction of more than 200 nm pore. Its microstructure would be destroyed, thus its mechanical property was decreased.

phosphogypsumcomposite cementing materialmechanical propertypore structure

张毅、王小鹏、李东旭

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南京工业大学,材料科学与工程学院,材料化学工程国家重点实验室,江苏,南京,210009

磷石膏 复合胶凝材料 力学性能 孔结构

国家科技支撑计划

2006BAJ04A04-02

2011

南京工业大学学报(自然科学版)
南京工业大学

南京工业大学学报(自然科学版)

CSTPCDCHSSCD北大核心
影响因子:0.313
ISSN:1671-7627
年,卷(期):2011.33(1)
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