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电化学膜生物反应器处理猪场污水运行效果

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针对目前膜生物反应器(Membrane bioreactor,MBR)处理污水时存在严重的膜污染问题,结合微生物燃料电池(Microbial fuel cell,MFC)处理污水时可产生电能的特点,本研究耦合MBR与MFC,构建新型电化学膜生物反应器(Electrochemistry membrane bioreactor,EMBR),探讨EMBR处理猪场污水的可行性,并对比评价闭路和开路连接方式的运行效果。结果表明,闭路EMBR可连续稳定运行。产电性能方面,最大功率密度、内阻和库仑效率分别为62。7 mW·m-2、229。1 Ω和15。5%;污染物去除方面,闭路EMBR对化学需氧量(COD)、氨氮(NH4+-N)、总氮(TN)和总磷(TP)的去除率分别为90。4%±0。5%、76。6%±1。8%、62。6%±1。6%和70。5%±3。4%,其中TN的去除率较开路EMBR系统显著提升了3。8%;膜污染减缓方面,闭路EMBR在其自身所产电场作用下可有效减缓膜污染,膜清洗周期较开路EMBR延长了30%。EMBR作为一种新兴污水处理技术,在高效去除猪场污水中污染物的同时可产生电能,并可利用自身所产电能原位减缓膜污染速率。
Study of swine farm wastewater treatment using electrochemical membrane bioreactor
Considering severe membrane fouling of the membrane bioreactor(MBR)and electricity generation characteristics of the microbial fuel cell(MFC)during wastewater treatment,this study constructed a novel electrochemical membrane bioreactor(EMBR)through integration of MBR and MFC.The feasibility and performance of swine farms wastewater treatment using EMBR were investigated in closed-circuit and open-circuit connections.The closed-circuit EMBR achieved a continuous and stable operation.Regarding power generation,the maximum power density,internal resistance,and Coulombic efficiency were 62.7 mW·m-2,229.1 Ω,and 15.5%,respectively.The removal rate of the closed-circuit EMBR for chemical oxygen demand(COD),ammonium(NH4+-N),total nitrogen(TN),and total phosphorus(TP)were 90.4%±0.5%,76.6%±1.8%,62.6%±1.6%,and 70.5%±3.4%,respectively.Compared with the open-circuit EMBR system,the removal rate of TN increased by 3.8%.The closed-circuit EMBR could effectively mitigate membrane contamination owing to its own generated electric field,and the membrane cleaning cycle was extended by 30%compared to that for the open-circuit EMBR.As an emerging wastewater treatment technology,EMBR can generate electricity for in-situ mitigation of membrane contamination and efficiently remove pollutants from swine farm wastewater.

electrochemistry membrane bioreactorswine farmwastewaterelectricity generationpollutantmembrane fouling

刘壮壮、刘崇涛、吴厚凯、宋建超、李洋洋、陶秀萍、鞠然

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中国农业科学院农业环境与可持续发展研究所,北京 100081

中国农业科学院都市农业研究所,成都 610200

电化学膜生物反应器 猪场 污水 产电性能 污染物 膜污染

中国农业科学院科技创新工程项目(ASTIP-CAAS)中国农业科学院杰出人才支持计划项目

NKYCLJ-C-2021-029

2024

农业环境科学学报
农业部环境保护科研监测所 中国农业生态环境保护协会

农业环境科学学报

CSTPCD北大核心
影响因子:1.52
ISSN:1672-2043
年,卷(期):2024.43(8)