首页|氮掺杂碳包覆的氧化镍和钼酸镍复合材料用于尿素氧化电催化

氮掺杂碳包覆的氧化镍和钼酸镍复合材料用于尿素氧化电催化

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通过分步水热以及退火的方法合成了氮掺杂碳包覆的氧化镍和钼酸镍复合材料(C-N@NiO-NiMo O4),并将其负载于泡沫镍(NF)上,直接用作催化尿素氧化反应 UOR 的电极材料。实验表明:氮掺杂碳包覆结构以及C-N@NiO 与 NiMoO4 的协同作用可以增强催化剂的导电性、电荷转移能力、抗中毒能力并增大电活性表面积,显著提高了 C-N@NiO-NiMo O4的电催化活性和长期稳定性。研究还发现,C-N@NiO-NiMo O4/NF 在 1。8 V 的电流密度是NiMo O4/NF的 1。7 倍,C-N@NiO/NF的 3。6 倍,在 10 mA·cm-2 的电流密度下催化 UOR 57 h,催化性能无显著变化。综上,C-N@NiO-NiMo O4 具有良好的实际应用前景。
N-doped Carbon-encapsulated Nickel Oxide and Nickel Molybdate Composite for Urea Oxidation Electrocatalysis
In this paper,N-doped carbon-encapsulated nickel oxide and nickel molybdate composite(C-N@NiO-NiMo O4)was synthesized by stepwise hydrothermal as well as an-nealing methods,and was loaded on nickel foam(NF)for UOR electrocatalysis.The N-doped carbon-encapsulated structure and the synergistic effect of C-N@NiO and NiMo O4 can enhance the conductivity,charge transfer ability,poisoning resistance and increase the elec-troactive surface area,which significantly improve the electrocatalytic activity and long-term stability of the C-N@NiO-NiMo O4.It was found that the current density of C-N@NiO-Ni-Mo O4/NF at 1.8 V is 1.7 times higher than that of NiMo O4/NF and 3.6 times higher than that of C-N@NiO/NF.There was no significant change in the catalytic performance after 57 h of reaction at a current density of 10 mA·cm-2.The results showed that the prepared C-N@NiO-NiMo O4/NF has a good practical application prospect.

urea oxidationelectrocatalysisnickel oxidenickel molybdateN-doped car-bon-encapsulated structure

徐立强、杨星、张玉冰、王新星

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青岛科技大学 化学与分子工程学院,山东 青岛 266042

贵州红星发展股份有限公司,贵州 安顺 561206

尿素氧化 电催化 氧化镍 钼酸镍 氮掺杂碳包覆结构

国家自然科学基金青年项目光电传感与生命分析教育部重点实验室开放基金项目

21804076SATM201708

2024

青岛科技大学学报(自然科学版)
青岛科技大学

青岛科技大学学报(自然科学版)

CSTPCD
影响因子:0.297
ISSN:1672-6987
年,卷(期):2024.45(1)
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