首页|胶州湾沉积物的不同相态主量元素含量及铁同位素组成初探

胶州湾沉积物的不同相态主量元素含量及铁同位素组成初探

Content of Major Elements and Iron Isotopic Compositions in Different Fractions of Jiaozhou Bay Sediments

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沉积物是物源、沉积环境、生源过程等多因素影响下的产物,不同元素进入沉积物的方式不同导致其赋存在不同的相态中,通过研究不同相态沉积物的元素丰度及同位素组成,可以揭示由于多种过程混合所掩盖的生物、物理及化学信息.本研究通过选择性化学提取法,对胶州湾沉积物进行了分级提取,包括碳酸盐结合态、易还原的氧化物态、可还原的氧化物态、磁铁矿态和残留态.测试结果表明:主量元素主要赋存在残留态中,但在非残留态中不同程度保留有Ca、Fe、Mg、Mn和P.结合胶州湾沉积物中的常见矿物成分,除了之前研究已介绍的不同相态的目标矿物组成,推测易还原的氧化物态的潜在矿物还有独居石和磷灰石;可还原的氧化物态的潜在矿物还有褐铁矿;磁铁矿态的潜在矿物还有钛铁矿;部分硅酸盐矿物也存在于易还原的氧化物态和可还原的氧化物态中.残留态富集了重铁同位素,继承了物源区的特征,并且全组分的铁同位素主要受控于残留态;活性铁组分的铁同位素由于受到了非陆源组分的影响,导致同位素变化.
Sediments are the products influenced by multiple factors(such as,provenance,depositional environment,and biogenic process),different elements enter sediments in dif-ferent ways,resulting in their occurrence in different fractions.By studying the elements a-bundance and isotopic compositions of sediments,it can reveal biology,physical and chemi-cal information obscured by the mixing of various processes.In this study,the sediments of Jiaozhou Bay were fractionally extracted,including carbonate combined fraction,easily re-ducible oxide fraction,reducible oxide fraction,magnetite fraction and residual fraction.The results of element content in different fractions show that the major elements are mainly present in the residual fraction,but Ca,Fe,Mg,Mn and P are present in the non-residual fractions to varying degrees.Combined with the common mineral compositions in the sedi-ments of Jiaozhou Bay,in addition to the target mineral compositions of different fractions introduced in previous studies,it is speculated that the potential minerals in the easily reduc-ible oxide fraction may include monazite and apatite.The potential minerals in the reducible oxide fraction may include limonite.The potential minerals in the magnetite fraction may in-clude ilmenite.Some silicate minerals also exist in easily reducible oxide fraction and reduci-ble oxide fraction.The residual fraction is enriched with heavy iron isotope,inheriting the characteristics of the provenance area,and the iron isotope of the total fraction is mainly con-trolled by the residual fraction.The iron isotope of the active iron fraction is affected by the non-terrestrial compositions.

Jiaozhou Baysedimentssequential extractioniron isotope

孙子威、肖媛媛、张跃、刘瑾

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青岛科技大学 化学与分子工程学院

海洋科学与生物工程学院,山东 青岛 266042

青岛海洋科学技术国家重点实验室,山东 青岛 266061

中国科学院 海洋研究所地质与环境重点实验室

海洋大科学研究中心

海洋研究所公共技术服务中心,山东 青岛 266071

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胶州湾 沉积物 连续提取 铁同位素

青岛海洋科学与技术试点国家实验室重大项目(十四五)国家自然科学基金中国科学院战略性先导科技专项(B类)

LSKJ20220290541776069XDB42020302

2024

青岛科技大学学报(自然科学版)
青岛科技大学

青岛科技大学学报(自然科学版)

CSTPCD
影响因子:0.297
ISSN:1672-6987
年,卷(期):2024.45(2)
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