青岛科技大学学报(自然科学版)2024,Vol.45Issue(2) :56-63.DOI:10.16351/j.1672-6987.2024.02.007

新型树脂基金属有机骨架的制备及其对水体中阿洛西林钠的吸附性能

Preparation of a Novel Resin-Based Metal Organic Skeleton and Its Adsorption Performance on Sodium Aloxacillin in Water

厉佳音 钱翌 李龙 段英慧
青岛科技大学学报(自然科学版)2024,Vol.45Issue(2) :56-63.DOI:10.16351/j.1672-6987.2024.02.007

新型树脂基金属有机骨架的制备及其对水体中阿洛西林钠的吸附性能

Preparation of a Novel Resin-Based Metal Organic Skeleton and Its Adsorption Performance on Sodium Aloxacillin in Water

厉佳音 1钱翌 1李龙 1段英慧2
扫码查看

作者信息

  • 1. 青岛科技大学环境与安全工程学院,山东 青岛 266042
  • 2. 青岛科技大学化工学院,山东 青岛 266042
  • 折叠

摘要

通过在聚苯乙烯阴离子交换剂D201内合成UIO-66,制备复合吸附剂D201@UIO-66,用来去除水体药物污染.这种方法提高了金属有机骨架在液体中的结构稳定性并增强了吸附性能.通过XRD、SEM、EDS、FT-IR、BET等方式对复合吸附剂进行表征,结果表明,在D201中成功负载UIO-66.批量吸附实验表明,当复合吸附剂的用量为0.5 g·L-1 时,复合吸附剂的最大实验吸附量为142.5 mg·g-1.复合吸附剂在较宽pH范围内体现出吸附稳定性.在其他阴离子的干扰下,复合吸附剂仍对阿洛西林钠具有选择吸附性.吸附动力学过程与伪二级动力学吸附模型符合,吸附等温线与Langmuir模型更为符合.

Abstract

In this study,a composite adsorbent D201@UIO-66 was prepared by synthesizing UIO-66 within a polystyrene anion exchanger D201 and used to remove pharmaceutical con-tamination from water bodies.This approach improved the structural stability of the metal-organic backbone in the liquid and improved the adsorption performance.The composite ad-sorbent was characterized by XRD,SEM,EDS,FT-IR and BET,and the results showed that UIO-66 was successfully loaded in D201.The batch adsorption experiments showed that the maximum experimental adsorption capacity of the composite adsorbent was 142.5 mg·g-1 when the amount of composite adsorbent was 0.5 g·L-1.The composite adsor-bent exhibited adsorption stability over a wide pH range.The composite adsorbent showed selective adsorption of sodium aloxacillin in the presence of other anions.The adsorption ki-netics were consistent with the pseudo-secondary kinetic adsorption model,and the adsorp-tion isotherms were more consistent with the Langmuir model.The composite adsorbent D201@UIO-66 has good potential for the adsorption of pharmaceutical contamination in water.

关键词

纳米复合吸附剂/UIO-66/阿洛西林钠/吸附/选择性

Key words

nanocomposites/UIO-66/aloxicillin sodium/adsorbent/selectivity

引用本文复制引用

基金项目

山东省自然科学基金(ZR2021ME170)

山东省自然科学基金(ZR2021MB028)

出版年

2024
青岛科技大学学报(自然科学版)
青岛科技大学

青岛科技大学学报(自然科学版)

CSTPCD
影响因子:0.297
ISSN:1672-6987
参考文献量21
段落导航相关论文