青岛科技大学学报(自然科学版)2024,Vol.45Issue(6) :79-84.DOI:10.16351/j.1672-6987.2024.06.010

双电性β-甲壳素纳米纤维的制备及其在皮克林乳液中的应用

Preparation of Zwitterionic β-chitin Nanofibers and Its Application in Pickering Emulsion

刘大营 徐凯 黄莎莎 张建明
青岛科技大学学报(自然科学版)2024,Vol.45Issue(6) :79-84.DOI:10.16351/j.1672-6987.2024.06.010

双电性β-甲壳素纳米纤维的制备及其在皮克林乳液中的应用

Preparation of Zwitterionic β-chitin Nanofibers and Its Application in Pickering Emulsion

刘大营 1徐凯 1黄莎莎 1张建明1
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作者信息

  • 1. 青岛科技大学高分子科学与工程学院;橡塑材料与工程教育部重点实验室,山东青岛 266042
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摘要

开发了一种新型的双电性β-甲壳素纳米纤维.首先,以部分脱乙酰化的β-甲壳素为原料,经过TEMPO/NaClO2/NaClO氧化在其表面修饰上羧基官能团,然后再对其碱处理脱除乙酰氨基形成氨基,最后经过超声离心后获得了双电性β-甲壳素纳米纤维.该纳米纤维在酸性和碱性条件下良好的分散,具有广泛的pH稳定范围.通过调控双电性β-甲壳素纳米纤维表面电荷电离程度,纳米纤维在碱性条件下对环氧大豆油表现出了良好的乳化效果,展现了作为Pickering乳化剂的应用潜力.

Abstract

In this study,a novel zwitterionic β-chitin nanofiber was developed.Firstly,the partially deacetylated β-chitin was subjected to TEMPO/NaClO2/NaClO oxidation and car-boxyl groups were introduced into its surface,followed by alkali treatment to remove the acetylamino groups on chitin to form amino groups.Finally,after ultrasonic and centrifugal treatment,the zwitterionic β-chitin nanofibers were obtained.The nanofibers can be stably dispersed under acidic and alkaline conditions,which indicates that it has a good stability in a wide pH range.By modulating the degree of charge ionization on the surface of the zwitteri-onic β-chitin nanofibers,the nanofibers showed good emulsification of epoxidized soybean oil under alkaline conditions,demonstrating its potential application as Pickering emulsifier.The development of this novel zwitterionic β-chitin nanofiber is helpful to promote the appli-cation of chitin nanomaterials.

关键词

甲壳素纳米纤维/β-甲壳素/TEMPO氧化/碱处理/双电性

Key words

chitin nanofibers/β-chitin/TEMPO oxidation/alkali treatment/zwitterionic

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出版年

2024
青岛科技大学学报(自然科学版)
青岛科技大学

青岛科技大学学报(自然科学版)

CSTPCD
影响因子:0.297
ISSN:1672-6987
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