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碳纳米管导电膜原位电化学清洗缓解膜污染研究

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应用周期性电化学清洗方法,系统评价电化学清洗缓解超滤膜有机、生物及有机/生物混合污染的效果及作用机理.采用真空抽滤方式制备碳纳米管(CNT)-聚四氟乙烯(PTFE)导电膜,研究电化学清洗对缓解海藻酸钠(SA)、铜绿假单胞菌(PA)及两者混合污染后标准化膜通量恢复效果.结果表明,经SA、PA及两者混合污染后,标准化膜通量均迅速下降,而电化学清洗通过直接氧化与间接氧化相结合的方式,使标准化膜通量分别恢复至初始通量的 99%、74%和 94%.此外,在 3 V电压下持续电化学清洗 3 min,截留在膜面的活细菌从 6×106 CFU/cm2 降低为 6 CFU/cm2,去除率达到 6 log.
In-situ electrochemical cleaning of carbon nanotube conductive membrane in alleviating membrane fouling
In this study,periodic electrochemical cleaning was applied to systematically eval-uate the effect and mechanism of electrochemical cleaning in alleviating organic,biological and mixed fouling of ultrafiltration membranes.Carbon nanotube(CNT)-polytetrafluoro-ethylene(PTFE)conductive membrane was prepared by vacuum filtration,and the effect of electrochemical cleaning on alleviating the fouling of sodium alginate(SA),Pseudomonas aeruginosa(PA)and the mixed fouling was assessed.The results indicated that the mem-brane flux decreased rapidly after SA,PA and mixed fouling,but then restored to 99%,74%and 94%of the initial flux respectively after the electrochemical cleaning which com-bined direct oxidation and indirect oxidation.Additionally,the living bacteria trapped on the membrane surface were reduced from 6×106 CFU/cm2 to 6 CFU/cm2,and the removal effi-ciency reached 6 log by continuous electrochemical cleaning with an applied voltage of 3 V for 3 minutes.

electrochemical cleaningcarbon nanotubeconductive membranemembrane fouling

王凌雪、于童、王子维、杨英杰、李苹、施雪卿

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青岛理工大学 环境与市政工程学院,青岛 266525

电化学清洗 碳纳米管 导电膜 膜污染

中国博士后科学基金面上资助项目青岛市博士后研究人员应用研究项目

2019M652347

2024

青岛理工大学学报
青岛理工大学

青岛理工大学学报

影响因子:0.514
ISSN:1673-4602
年,卷(期):2024.45(2)
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