首页|基于响应面法地质聚合物固化黏土力学性能试验研究

基于响应面法地质聚合物固化黏土力学性能试验研究

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地质聚合物是一种硬化快、强度高、耐久性好的绿色胶凝材料,通过添加地质聚合物胶凝材料矿渣、电石渣以及碱激发剂CaO、NaHCO3来进行固化黏土试验研究.影响因素为矿渣掺量、电石渣掺量、碱激发剂掺量,响应值为7、28 d固化土抗压强度,利用Box-Behnken试验,分析获得最优配合比.结果表明:养护龄期7 d时,矿渣掺量影响最大;养护龄期28 d时,碱激发剂掺量影响最大.固化土预测抗压强度和实际抗压强度较为接近,模型可靠性较高.矿渣掺量为17.37%、电石渣掺量为9.31%、碱激发剂掺量为6.51%,7 d龄期抗压强度目标值达到612.97 kPa,28 d龄期抗压强度目标值达到875.69 kPa.经SEM分析,7 d主要水化产物为絮状C-S-H凝胶,随着养护龄期的增加,絮状C-S-H凝胶逐渐形成了三维网状C-S-H凝胶.随着钙矾石的生成,针状钙矾石和C-S-H凝胶共同填充固化土颗粒间孔隙,使固化土力学性能得到提升.
Experimental study on the mechanical properties of geopolymer solidified clay based on response surface method
Geopolymer is a kind of green cementing material with fast hardening,high strength and good durability.In this study,the experimen on clay solidification was carried out by adding such geopolymer cementing materials as slag,calcium carbide slag and alkali activators CaO and NaHCO3.With the influencing factors of slag content,calcium carbide slag content and alkali initiator content,and with the response values of 7 and 28 days of so-lidified soil compressive strength,the optimal mix ratio was obtained through Box-Behnken test.The results showed that the slag dosage had the greatest effect at 7 days of maintenance age,and the alkali stimulant dosage had the greatest effect at 28 days of maintenance age.The predicted compressive strength of the solidified soil was close to the actual compressive strength,and the reliability of the model was high.When the slag content was 17.37%,the calcium carbide slag content was 9.31%and the alkali activator content was 6.51%,the tar-get value of the compressive strength reached 612.97 kPa at the 7 days and 875.69 kPa at the 28 days.According to SEM analysis,the main hydration product for 7 days was flocculent C-S-H gel,and with the increase of curing age,the flocculent C-S-H gel gradually formed a three-dimensional network C-S-H gel.With the formation of ettringite,acicular ettringite and C-S-H gel filled the intergranular pores of solidified soil,which improved the mechanical properties of solidified soil.

slagcalcium carbide slagresponse surface methodgeopolymer

张青云、张鹏

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青岛理工大学土木工程学院,青岛 266525

矿渣 电石渣 响应面法 地质聚合物

2024

青岛理工大学学报
青岛理工大学

青岛理工大学学报

影响因子:0.514
ISSN:1673-4602
年,卷(期):2024.45(6)