首页|胡椒果与胡椒叶精油化学成分分析

胡椒果与胡椒叶精油化学成分分析

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采用水蒸气蒸馏法提取胡椒鲜果、黑胡椒、白胡椒和胡椒叶中的精油,得率分别为1.46%、1.77%、2.30%和1.25%.对精油进行GC-MS分析,分别鉴定得到38、31、36和63种化学物质,δ-榄香烯、3-蒈烯、D-柠檬烯、α-古巴烯、石竹烯和律草烯在果与叶中含量均较高,其中叶中δ-榄香烯含量占38.54%;蒎烯、月桂烯、α-水芹烯和间伞花素在果中含量较高,而在叶中含量较低;甘香烯、α--荜澄茄油烯、β-榄香烯、α-古芸烯、β-古巴烯、α-蛇床烯、花柏烯、4-异亚丙烯-7-甲基-6-亚甲基-2-辛烯酸甲酯和桉油烯醇在叶中含量较高,而果中含量较低或没有.此外,采用电子鼻方法可有效区分胡椒粉和胡椒叶.
Analysis of the Essential Oil Distilled from the Fruits and Leaves of Piper nigrum L.
The essential oil of the pepper fruits (fresh、black and white) and leaves were extracted by steam distillation and analyzed by GC-MS.The yields of them are 1.46%,1.77%,2.30% and 1.25%,respectively.And 38、31、36 and 63 chemical components were identified in the the essential oil,respectively.The contents of δ-elemene,3-Carene,D-limonene,alfa-copaene,caryophyllene and humulene are higher in fruits and leaves than others,and the content of δ-elemene in leaves is 38.54%.The contens of pinene,beta-myrcene,alphaphellandrene and M-cymene are much higher in the fruits than in the leaves,and the contens of 1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethenylidene)-cyclohexane,alpha-cubebene,β-elemene,α-Gurjunene,beta-copaene,α-selinene,beta-chamigrene,4-isopropylidene-7-methyl-6-methylene-2-octenoic acid methyl ester and Spathulenol are much higer in leaves than in fruits.Besides,using electronic nose,the different pepper powder can be distinguished effectively.

Piper nigrum LPepper leavesEssential oilGC-MSElectronic nose

张水平、谷风林、吴桂苹、王庆煌

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中国热带农业科学院香料饮料研究所,海南万宁 571533

华中农业大学食品科学技术学院,湖北武汉 430070

农业部香辛饮料作物遗传资源利用重点实验室,海南万宁 571533

国家重要热带作物工程技术研究中心,海南万宁 571533

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胡椒 胡椒叶 精油 GC-MS 电子鼻

国家科技支撑计划课题国家重大科技成果转化项目

2012BAD36B03

2014

热带作物学报
中国热带作物学会

热带作物学报

CSTPCDCSCD北大核心
影响因子:0.807
ISSN:1000-2561
年,卷(期):2014.35(2)
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