首页|脉冲电镀Ni-Cr-Mn合金镀层配位剂的研究

脉冲电镀Ni-Cr-Mn合金镀层配位剂的研究

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利用脉冲电镀方法在Q235钢表面制备Ni-Cr-Mn 合金镀层.采用辉光放电光谱仪、电化学工作站等设备,研究了不同的配位剂:甲酸铵、柠檬酸铵、复合配位剂A对Ni-Cr-Mn 合金镀层成分、沉积速率及耐蚀性的影响.结果表明,三种不同的配位剂对Ni-Cr-Mn 合金镀层成分、沉积速率及耐蚀性的影响相同.随着配位剂含量的增加,镀层中Cr、 Mn 含量先升高后降低,Ni 含量先降低后升高;然而沉积速率先升后降;复合配位剂A制备的Ni-Cr-Mn 合金镀层,具有最小的腐蚀电流密度、最大的腐蚀电位,分别为9.374×10-8 A/cm2、-0.288 V,耐蚀性更佳.
Study on Complexing Agent of Pulse Electroplating Ni-Cr-Mn Alloy Coating
Ni-Cr-Mn alloy coating was obtained on Q235 steel surface by pulse electroplating. The effects of different complexing agents such as ammonium formate, ammonium citrate and compound complexing agent Aon the composition, deposition rate as well as corrosion resistance of Ni-Cr-Mn alloy coating were investigated by glow discharge spectroscopy and electrochemical work station. The results show that the effects of three different complexing agents on the composition, deposition rate and corrosion resistance of Ni-Cr-Mn alloy coating are similar. With complexing agents content increasing, the contents of Cr and Mn of the coating increases firstly and then decrease, but the content of Ni decreases firstly and then increases, and the deposition rate increase firstly and then decreases. The Ni-Cr-Mn alloy coating prepared in the compound complexing agent Ahas the minimum corrosion current density and the maximum corrosion potential, which is 9. 374 ×10-8 A/cm2 and -0. 288 V, then, the corrosion resistance is better.

pulse electroplatingNi-Cr-Mn alloy coatingcomplexing agentcorrosion resistance

张志桐、刘海鹏、王心悦、孟庆波、李运刚、杨海丽

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华北理工大学冶金与能源学院现代冶金技术教育部重点实验室, 河北唐山 063009

脉冲电镀 Ni-Cr-Mn合金镀层 配位剂 耐蚀性

国家自然科学基金资助项目

51474088

2017

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCDCSCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2017.46(18)
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