首页|32Cr3Mo1V表面激光熔覆TiC/钴基高温合金组织和性能研究

32Cr3Mo1V表面激光熔覆TiC/钴基高温合金组织和性能研究

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针对铝热轧辊套表面因高温摩擦磨损失效的问题,采用同轴送粉式激光熔覆在32Cr3Mo1V表面制备不同质量分数(0%、5%、10%、15%)TiC/Co-08 高温耐磨熔覆涂层.分析了该熔覆层的显微组织形貌、相组成及微区成分;测试了显微硬度、高温摩擦磨损性能.结果表明,Co-08 涂层主要由γ-Co及晶间碳化物组成,其磨损形式为氧化磨损和磨粒磨损.TiC添加量为5%时,晶间组织碳化物含量减少,涂层中Fe元素含量升高,涂层显微硬度降低,摩擦系数有所升高,磨损形式为粘着磨损和磨粒磨损.TiC含量≥10%时,晶间碳化物含量升高,涂层中析出细小的TiC颗粒,有效提高了涂层的显微硬度,其摩擦系数也明显降低,磨损机制主要为氧化磨损及轻微的磨粒磨损.当TiC添加量为 5%时,涂层显微组织变得粗大且显微硬度及高温耐磨性均降低.随着TiC含量的继续增加,涂层中重新析出小尺寸TiC增强体,且晶间碳化物含量也有所上升,其显微硬度及高温耐磨性也随TiC含量的增加而升高.在TiC含量≥10%时,TiC/Co-08 复合涂层具有良好的高温耐磨性.
Study on Microstructure and Properties of TiC/Cobalt Base Superalloy by Laser Cladding on 32Cr3Mo1V Surface
In view of the failure of the surface of aluminothermic roll sleeve due to high temperature friction and wear,the high temperature wear-resistant cladding coatings of Co-08 with different mass fraction(0%,5%,10%,15%)TiC were prepared on the surface of 32Cr3Mo1V by coaxial powder feeding laser cladding.The microstructure,phase composition and micro zone composition of the cladding layer were analyzed,and the microhardness and high temperature friction and wear properties were tested.The results show that Co-08 coating is mainly composed of γ-Co and carbide intergranular,the wear forms are oxidation wear and abrasive wear.When the addition amount of TiC is 5%,the content of carbide in the intergranular structure decreases,the content of Fe element in the coating increases,the microhardness decreases,the friction coefficient increases,and the wear form changes from oxidation wear to adhesive wear and abrasive wear.When TiC content is greater than or equal to 10%,the content of intergranular carbide increases,and fine TiC particles are precipitated in the coating,which effectively improves the microhardness of the coating and significantly reduces its friction coefficient.The wear mechanism is mainly oxidation wear and slight abrasive wear.When the addition amount of TiC is 5%,the microstructure of the coating becomes coarse and the microhardness and high-temperature wear resistance decrease.With the continuous increase of TiC content,small-size TiC reinforcements are reprecipitated in the coating,and the content of intergranular carbides also increases.The microhardness a nd high temperat ure wear resistance also increase with the increase of TiC content.When TiC content is greater than or equal to 10%,TiC/Co-08 composite coating has good high temperature wear resistance.

Co based alloylaser claddingTiCmicrostructurehigh temperature friction and wear

尹燕、周炜、李辉、龚岩、张潇、张瑞华

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兰州理工大学 省部共建有色金属先进加工与再利用国家重点实验室, 甘肃 兰州 730050

中国钢研科技集团有限公司, 北京 100081

阳江市五金刀剪产业技术研究院, 广东 阳江 529533

Co基合金 激光熔覆 TiC 显微组织 高温摩擦磨损

国家自然科学基金阳江市高功率应用实验室有限公司支持粤东西北新型研发机构建设项目海上风电高速激光熔覆防腐涂层制备工艺及应用项目

5216100720180902SDZX202009

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(2)
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