首页|SUS321不锈钢表面Cr/CrN涂层的制备与抗氧化及耐腐蚀研究

SUS321不锈钢表面Cr/CrN涂层的制备与抗氧化及耐腐蚀研究

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采用磁控溅射技术,在SUS321 不锈钢表面制备Cr/CrN涂层,利用扫描电子显微镜(SEM)、X射线衍射仪(XRD)及分析天平等分别表征样品高温氧化及酸性盐雾腐蚀实验后的微结构及增重.结果表明,当磁控溅射气体分压比为PAr/PN2=3∶1 的涂层样品抗氧化性能及耐腐蚀性能最佳.在此基础上通过循环沉积制备了多层Cr/CrN涂层,6 周期涂层样品在600℃氧化200 h后的单位面积增重为3.599 g/m2,表面氧化膜致密,没有出现剥落现象;6 周期的涂层样品在酸性盐雾环境中能够保持480 h表面无变化,在放置500 h后边缘部位才开始出现轻微锈迹.固定磁控溅射气体分压比为PAr/PN2=3∶1 时,制备的6周期Cr/CrN多层膜涂层具有最佳的抗氧化及耐酸性盐雾腐蚀性能.
Research on Preparation,Oxidation Resistance and Corrosion Resistance of Cr/CrN Coating on SUS321 Stainless Steel Surface
Cr/CrN coatings were prepared on the surface of SUS321 stainless steel using magnetron sputtering technology.The microstructure and weight gain of samples after high-temperature oxidation and acidic salt spray corrosion experiments were characterized using scanning electron microscopy(SEM),X-ray diffraction(XRD)and analytical balance.The results show that the sample with a magnetron sputtering pressure ratio of PAr/PN2=3∶1 exhibits the best antioxidation and corrosion resistance.Based on this,multi-layer Cr/CrN coatings are prepared through cyclic deposition.The sample with 6-cycle coatings has a weight gain of 3.599 g/m2 after oxidation at 600℃for 200 h,with a dense surface oxide film and no peeling observed.In an acidic salt spray environment,the sample with a 6-cycle coating has no obvious oxidation for 480 h,and generates slight rust only at the edge after oxidation for 500 h.The 6-cycle Cr/CrN multilayer film coating prepared with a fixed magne tron sputtering pressure ratio of PAr/PN2=3∶1 exhibits the best antioxidation and resistance to acidic salt spray corrosion.

SUS321 stainless steelmagnetron sputteringCr/CrN coatingantioxidation performancecorrosion resistance

张林嘉、卢婷、李恒、李亚茹、许海龙

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海军装备广州局贵阳军代室,贵州 贵阳 550018

中国航发四川燃气涡轮研究院,四川 成都 610500

西北工业大学,陕西 西安 710072

SUS321不锈钢 磁控溅射 Cr/CrN涂层 抗氧化性能 耐腐蚀性能

国家自然科学基金

31800802

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(6)
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