首页|不同炉中钎焊气氛对不锈钢耐腐蚀性能的影响

不同炉中钎焊气氛对不锈钢耐腐蚀性能的影响

扫码查看
考虑企业生产的安全性和经济性,家用燃气快速热水器用铜制热交换器炉中钎焊工艺的保护气氛由氨分解气气氛改为天然气气氛,但发现热交换器水道管路中 304 不锈钢扰流弹簧易产生氧化腐蚀.本文以 430 和 304 不锈钢扰流弹簧为研究对象,将弹簧在氨分解气与天然气气氛的网带式高温钎焊炉中进行 800~830℃的钎焊,然后进行24、48 h的大气氧化试验,以及 72 h的中性盐雾试验,研究了高温条件下氨分解气与天然气气氛对不锈钢材料耐腐蚀性能的影响.结果表明:经过氨分解气和天然气气氛钎焊的 304 不锈钢扰流弹簧在 24、48 h大气氧化试验后均产生明显腐蚀,且天然气保护气氛加剧了其腐蚀程度.炉中钎焊温度 800~830℃达到 304 不锈钢材料的敏化温度区间,导致晶间腐蚀,对其抗氧化性能具有明显的影响,而对 430 不锈钢材料并未有明显影响.430 不锈钢在同等条件下的耐腐蚀性能优于 304 不锈钢.建议热交换器水道管路中的扰流弹簧选择 430 不锈钢.
Effect of Different Brazing Atmospheres in Furnace on Corrosion Resistance of Stainless Steels
Considering the safety and economy of enterprise production,the protective atmosphere in the brazing process of copper heat exchanger for domestic gas instantaneous water heater is changed from ammonia decomposition gas atmosphere to natural gas atmosphere.It is prone to oxidation corrosion for 304 stainless steel spoiler spring in water channel of a heat exchanger.Taking 430 and 304 stainless steel spoiler springs as the object,the springs were brazed at 800-830℃in a mesh belt high temperature brazing furnace with ammonia decomposition gas and natural gas atmosphere,then the atmospheric oxidation test for 24,48 h and neutral salt spray test for 72 h were carried out.The influence of ammonia dissociation gas and natural gas atmosphere at high temperature on the corrosion resistance of the stainless steels was studied.The results show that the 304 stainless steel spoiler spring brazed by ammonia decomposition gas and natural gas atmosphere produces obvious corrosion after 24 and 48 h atmospheric oxidation test,and the natural gas protection atmosphere aggravates its corrosion degree.The brazing temperature in the furnace of 800-830℃reaches the sensitization temperature range of 304 stainless steel,resulting in intercrystal corrosion,and it has an obvious impact on its oxidation resistance,but has no obvious impact on 430 stainless steel material.The corrosion resistance of 430 stainless steel is better than that of 304 stainless steel under the same conditions.It is recommended to choose 430 stainless steel spring in heat exchanger channel pipeline.

ammonia decomposition gasnatural gasstainless steelcorrosion resistance

黄昌文、陈建平、林泓延

展开 >

广东万和新电气股份有限公司 热厨制造中心,广东 佛山 528305

佛山职业技术学院 智能制造学院,广东 佛山 528317

广东技术师范大学 机电学院,广东 广州 510630

氨分解气 天然气 不锈钢 耐腐蚀性

广东省普通高等学校重点科研平台和科研项目中国职业技术教育学会一般课题

2020KQNCX2102021B168

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(9)
  • 9