首页|AZ31B镁合金表面镍基复合镀层的制备及耐蚀性能研究

AZ31B镁合金表面镍基复合镀层的制备及耐蚀性能研究

Research on Preparation and Corrosion Resistance of Nickel-based Composite Plating on AZ31B Magnesium Alloy Surface

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为了提高镁合金的耐腐蚀性,以AZ31B镁合金为基体,采用化学镀与脉冲电镀技术在其表面制备了Ni-P/Ni复合镀层.采用扫描电镜(SEM)、X射线衍射(XRD)分析了镀层表面的形貌和成分.通过电化学极化、阻抗测试和接触角研究了该复合镀层的耐腐蚀性和疏水性.结果表明:峰值电流密度为 30 mA/cm2 时,镀层的晶粒最细致,接触角最高为 117.3°,自腐蚀电位最高(-0.4510 V),腐蚀电流密度最低(1.94×10-7 A/cm2),阻抗值最大,明显优于镁合金基体,这说明该复合镀层可提高镁合金疏水性和耐腐蚀性.
In order to improve the corrosion resistance of magnesium alloy,Ni-P/Ni composite coating was prepared on the surface of AZ31B magnesium alloy using chemical plating and pulse plating techniques.Scan electron microscope(SEM)and X-ray diffractometer(XRD)were employed to detect the surface morphology and composition of the composite coating.Besides,the corrosion resistance and hydrophobicity of the composite coating were investigated by electrochemical polarization,impedance tests and contact angle tests.The results show that with the peak current density of 30 mA/cm2,the coating has the most detailed grain,the highest contact angle of 117.3°,the highest self-corrosion potential(-0.4510 V),the lowest corrosion current density(1.94×10-7 A/cm2),and the largest impedance value,which is obviously better than that of the magnesium alloy matrix,indicating that the composite coating could improve the hydrophobicity and corrosion resistance of magnesium alloy.

magnesium alloyelectroless platingpulse platingcorrosion resistancehydrophobicity

李昆达、张建强、赵慧敏、范爱兰、班美丽

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太原理工大学 材料科学与工程学院,山西 太原 030024

山西能源学院,山西 晋中 030604

镁合金 化学镀 脉冲电镀 耐腐蚀性 疏水性

国家自然科学基金材料腐蚀与防护四川省重点实验室开放基金

516711402021CL22

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(10)