首页|Y改性Cr-Al渗层的组织及抗热冲击性能

Y改性Cr-Al渗层的组织及抗热冲击性能

Microstructure and Thermal Shock Resistance of Y Modified Cr-Al Coating

扫码查看
采用粉末包埋渗法在DZ125 镍基合金表面制备了Cr-Al-Y渗层.借助扫描电镜、能谱仪及X射线衍射仪,对Cr-Al-Y渗层组织结构及相组成进行了分析表征,对比研究了DZ125 镍基合金基体及Cr-Al-Y渗层的抗热冲击性能.结果表明:经 1050℃保温 4 h所制备的Cr-Al-Y渗层均匀、致密、连续,厚度约为 120 μm,具有明显的沉积-扩散分布特征,渗层由外向内依次为Ni3Cr2、Ni3Al浅表层,富含Ni3Al的Ni3Cr2 外层、Ni3Cr2 中间层和Ni3Cr2、Ni3Al内层.1000℃热冲击实验显示,DZ125 基体热冲击 31 次后出现点状剥落,热冲击 114 次后目视可见裂纹,热冲击 145 次后表面出现块状剥落.Cr-Al-Y渗层热冲击 142 次后在渗层边缘出现细小裂纹,热冲击 181 次后出现可视细小裂纹,但渗层未出现剥落现象.这表明Cr-Al-Y渗层与基体合金之间不但具有良好的膜基结合力,还能在一定程度上提升DZ125 基体合金的抗热冲击性能.
Cr-Al-Y coating was prepared on the surface of DZ125 nickel base alloy by pack cementation process.The microstructure and phase composition were analyzed and characterized by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The thermal shock resistance of DZ125 nickel base alloy and Cr-Al-Y coatings were compared.The results show that Cr-Al-Y coating prepared by holding at 1050℃for 4 h is 120 μm thick and has a uniform,dense and continuous microstructure,and has a multi-layered structure with a superficial layer composed of Ni3Cr2 and Ni3Al,an outer layer composed of Ni3Al-rich Ni3Cr2,a middle layer composed of Ni3Cr2 and an inner layer composed of Ni3Cr2 and Ni3Al.DZ125 matrix under the thermal shock tested at 1000℃shows that the spot spalling occurs after 31 times,visible cracks occur after 114 times,and massive spalling appears on the surface after 145 times.However,small cracks appear at the edge of the Cr-Al-Y coating after 142 times of thermal shock,and visible small cracks appear after 181 times of thermal shock,but the coating does not peel off,which indicate that the Cr-Al-Y coating has good film base bonding ability with DZ125 alloy,which can improve the thermal impact resistance of DZ125 alloy to a certain extent.

DZ125 alloyCr-Al-Y coatingmicrostructurethermal shock

田兴达、梁国栋、王存喜、刘树静、李涌泉

展开 >

北方民族大学 材料科学与工程学院,宁夏 银川 750021

北方民族大学 机电工程学院,宁夏 银川 750021

DZ125合金 Cr-Al-Y渗层 显微组织 热冲击

国家自然科学基金国家自然科学基金宁夏回族自治区自然科学基金服务宁夏九大产业研究项目

51961003521610092020AAC02025FWNX42

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(10)