微量In对Mg-4Sn合金微观组织、电化学行为和放电性能的影响
Effect of Trace In on Microstructure,Electrochemical Behavior and Discharge Performance of Mg-4Sn Alloy
张研研 1张忠涛 2王勋 1李航1
作者信息
- 1. 太原理工大学 材料科学与工程学院,山西 太原 030024
- 2. 金龙精密铜管集团股份有限公司,重庆 404188
- 折叠
摘要
向铸态Mg-4Sn合金中添加 1.0wt%In,研究了微量In对合金微观组织、电化学行为和放电性能的影响.结果表明,添加In元素前后,合金的微观组织均由树枝晶形态的α-Mg基体以及在枝晶间弥散分布的Mg2Sn相组成.添加In元素后,In固溶于基体中,且合金的树枝晶尺寸变小,Mg2Sn相的均匀性提高;合金的开路电位更负,自腐蚀电流密度更低;在电池性能的测试中,合金表现出更平稳的放电过程、更负的放电电位和更高的阳极效率.这主要归因于加入In后合金更高的放电活性和更疏松的放电产物.
Abstract
1.0wt%In was introduced to Mg-4Sn cast alloy,and the effects of trace In on its microstructure,electrochemical property and discharge performance were studied.The result shows that the microstructure of the alloy before and after adding In element consists of dendritic α-Mg matrix and a small amount of Mg2Sn phase scattered along grain boundary.After the addition of In,it dissolves into the matrix,and the dendritic crystal size decreases,the uniformity of Mg2Sn phase improves,the open circuit potential of the alloy is more negative,the self-corrosion current density is lower.In the battery performance testing,the alloy with addition of In shows a smoother discharge process,more negative discharge potential and bigger anode efficiency.This is mainly attributed to the higher discharge activity and looser discharge products of the alloy after the addition of In.
关键词
镁空气电池/Mg-Sn合金/微观组织/电化学性能/放电性能Key words
Mg-air battery/Mg-Sn alloy/microstructure/electrochemical property/discharge performance引用本文复制引用
基金项目
国家自然科学基金资助项目(51901153)
山西省应用基础研究计划项目(201901D211096)
出版年
2024
NETL
NSTL
万方数据