热加工工艺2024,Vol.53Issue(14) :42-46.DOI:10.14158/j.cnki.1001-3814.20202646

电流模式对Mg-Zn-Ca镁合金微弧氧化涂层孔隙及耐腐蚀性的影响

Effects of Current Mode on Porosity and Corrosion Resistance of Micro-arc Oxidation Ceramic Coating on Mg-Zn-Ca Magnesium Alloy

汤晓刚 张莉 陈磊
热加工工艺2024,Vol.53Issue(14) :42-46.DOI:10.14158/j.cnki.1001-3814.20202646

电流模式对Mg-Zn-Ca镁合金微弧氧化涂层孔隙及耐腐蚀性的影响

Effects of Current Mode on Porosity and Corrosion Resistance of Micro-arc Oxidation Ceramic Coating on Mg-Zn-Ca Magnesium Alloy

汤晓刚 1张莉 1陈磊2
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作者信息

  • 1. 安徽华电工程咨询设计有限公司,安徽 合肥 230022
  • 2. 北京航空航天大学 合肥创新研究院,安徽 合肥 230012
  • 折叠

摘要

分别采用单极、双极和混合电流模式在Mg-Zn-Ca合金基板上制备 3 种微弧氧化涂层.通过扫描电镜(SEM)和三维激光扫描共聚焦显微镜测量了涂层的孔隙尺寸、表面形貌和表面粗糙度,涂层的物相结构采用X射线衍射仪进行表征,应用电化学工作站和 500 h的盐雾腐蚀对 3 种涂层进行耐腐蚀性研究.结果表明:3 种涂层均主要由MgO、Mg2SiO4、Mg2SiO3 相组成,混合电流模式下得到的涂层表面光洁度更好,表面气孔尺寸达到(5.52±0.63)μm;同时较小的孔隙形成了屏障阻隔效应,使其耐蚀性高于单极和双极模式涂层的.

Abstract

Three kinds of micro-arc oxidation coatings were prepared on Mg-Zn-Ca alloy substrate by using unipolar,bipolar and hybrid mode.The surface pore and surface morphology of the coating were measured by scanning electron microscope and 3D laser scanning confocal microscope,respectively.X-ray diffractometer was used to analyze the phase structure of the coating.The corrosion resistance of three kinds of coatings was studied by electrochemical workstation and 500h salt spray corrosion experiment.The results show that the three coatings are mainly composed of MgO,Mg2SiO4 and Mg2SiO3 phases.The coating obtained under hybrid mode has better surface finish and the size of surface pore is(5.52±0.63)μm.Besides,the low porosity has a barrier effect,which makes the coating has a better corrosion resistance than those in unipolar and bipolar modes.

关键词

镁合金/微弧氧化/陶瓷层/耐腐蚀性/孔隙率

Key words

magnesium alloy/micro-arc oxidation/ceramic coating/corrosion resistance/porosity

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出版年

2024
热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
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